Talal Mallah
A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations. A. Colin, Y. Wang, F. Lambert, N. Bridonneau, N. Suaud, R. Guillot, E. Rivière, Z. Halime, N. Guihéry, S.-I. Ohkoshi, T. Mallah, Magnetochemistry, 2024, 10
Investigation of the spin crossover behaviour of a sublimable Fe(ii)-qsal complex: from the bulk to a submonolayer on graphene/SiO2. A. Trapali, M. Muppal, S. Pandey, M.-L. Boillot, V. Repain, Y. J. Dappe, J.-F. Dayen, E. Rivière, R. Guillot, M.-A. Arrio, E. Otero, A. Bellec, T. Mallah, Dalton Trans., 2024, 53, 12519-12526
Detection of a Jahn–Teller mode as an ultrafast fingerprint of spin-transition-induced charge transfer in CoFe Prussian Blue Analogue. M. Hervé, B. Marekha, S. Mazerat, T. Mallah, M. Cammarata, S. F. Matar, S. Haacke, J. Léonard, E. Collet, Mater. Adv., 2024
Understanding the Electronic Structure of Magnetic Trinuclear Complexes Based on the Tris-dioxolene Triphenylene Non-innocent Bridging Ligand, a Theoretical Study. N. Suaud, A. Colin, M. Bouammali, T. Mallah, N. Guihéry, Chemistry – A European Journal, 2023, n/a, e202302256
Optical Read-Out of the Electrical Switching of Cobalt-Terpyridine-BODIPY Molecules Immobilized as Single Layer on ITO. K. Magra, J.-F. Audibert, D. Dragoe, T. Mallah, F. Miomandre, M.-L. Boillot, Advanced Optical Materials, 2023, 11, 2301128
Mechanoelastic simulations of monolayer lattices of spin crossover molecules on a substrate. A. Railean, M. Kelai, A. Bellec, V. Repain, M.-L. Boillot, T. Mallah, L. Stoleriu, C. Enachescu, Physical Review B, 2023, 107, 014304
Hybrid nanostructures based on gold nanoparticles and functional coordination polymers: Chemistry, physics and applications in biomedicine, catalysis and magnetism. R. Sanchis-Gual, M. Coronado-Puchau, T. Mallah, E. Coronado, Coordination Chemistry Reviews, 2023, 480, 215025
Interface versus Bulk Light-Induced Switching in Spin-Crossover Molecular Ultrathin Films Adsorbed on a Metallic Surface. M. Kelai, A. Tauzin, A. Railean, V. Repain, J. Lagoute, Y. Girard, S. Rousset, E. Otero, T. Mallah, M.-L. Boillot, C. Enachescu, A. Bellec, J. Phys. Chem. Lett., 2023, 14, 1949-1954
Unique Dimerization Topology and Countercation Binding Modes in 12-Metallacrown-4 Compounds. E. V. Salerno, C. M. Foley, V. Marzaroli, B. L. Schneider, M. D. Sharin, J. W. Kampf, L. Marchiò, M. Zeller, R. Guillot, T. Mallah, M. Tegoni, V. L. Pecoraro, C. M. Zaleski, European Journal of Inorganic Chemistry, 2022, 2022, e202200439
Out-of-equilibrium dynamics driven by photoinduced charge transfer in CsCoFe Prussian blue analogue nanocrystals. S. Zerdane, M. Hervé, S. Mazerat, L. Catala, R. Alonso-Mori, J. M. Glownia, S. Song, M. Levantino, T. Mallah, M. Cammarata, E. Collet, Faraday Discuss., 2022
XAS and XMCD Reveal a Cobalt(II) Imide Undergoes High-Pressure-Induced Spin Crossover. N. Bouldi, M. Mannini, M. Retegan, R. G. Miller, B. Cahier, P. Sainctavit, N. Guihéry, T. Mallah, D. Cabaret, D. Gouéré, F. Baudelet, L. Nataf, F. Wilhelm, F. Guillou, A. Rogalev, N. Suaud, S. Brooker, A. Juhin, J. Phys. Chem. C, 2022, 126, 5784-5792
Terphenylthiazole-based self-assembled monolayers on cobalt with high conductance photo-switching ratio for spintronics. V. Prudkovskiy, I. Arbouch, A. Léaustic, P. Yu, C. Van Dyck, D. Guérin, S. Lenfant, T. Mallah, J. Cornil, D. Vuillaume, Nanoscale, 2022, 14, 5725-5742
Robust magnetic anisotropy of a monolayer of hexacoordinate Fe(ii) complexes assembled on Cu(111). M. Kelai, B. Cahier, M. Atanasov, F. Neese, Y. Tong, L. Zhang, A. Bellec, O. Iasco, E. Rivière, R. Guillot, C. Chacon, Y. Girard, J. Lagoute, S. Rousset, V. Repain, E. Otero, M.-A. Arrio, P. Sainctavit, A.-L. Barra, M.-L. Boillot, T. Mallah, Inorg. Chem. Front., 2021, 8, 2395-2404
Voltage-Induced Bistability of Single Spin-Crossover Molecules in a Two-Dimensional Monolayer. Y. Tong, M. Kelaï, K. Bairagi, V. Repain, J. Lagoute, Y. Girard, S. Rousset, M.-L. Boillot, T. Mallah, C. Enachescu, A. Bellec, J. Phys. Chem. Lett., 2021, 12, 11029-11034
Magnetic Hysteresis in a Monolayer of Oriented 6 nm CsNiCr Prussian Blue Analogue Nanocrystals. L. Zhang, M.-A. Arrio, S. Mazerat, L. Catala, W. Li, E. Otero, P. Ohresser, L. Lisnard, C. Cartier Dit Moulin, T. Mallah, P. Sainctavit, Inorg. Chem., 2021, 60, 16388-16396
A high-frequency EPR study of magnetic anisotropy and intermolecular interactions of Co(II) ions. L. Spillecke, S. Tripathi, C. Koo, M. Ansari, S. Vaidya, A. Rasamsetty, T. Mallah, G. Rajaraman, M. Shanmugam, R. Klingeler, Polyhedron, 2021, 208, 115389
Collective Magnetic Behavior of 11 nm Photo-Switchable CsCoFe Prussian Blue Analogue Nanocrystals: Effect of Dilution and Light Intensity. L. Trinh, E. Rivière, S. Mazerat, L. Catala, T. Mallah, Magnetochemistry, 2021, 7
Thermal Bistability of an Ultrathin Film of Iron(II) Spin-Crossover Molecules Directly Adsorbed on a Metal Surface. M. Kelai, V. Repain, A. Tauzin, W. Li, Y. Girard, J. Lagoute, S. Rousset, E. Otero, P. Sainctavit, M.-A. Arrio, M.-L. Boillot, T. Mallah, C. Enachescu, A. Bellec, J. Phys. Chem. Lett., 2021, 12, 6152-6158
Magnetic properties of two GdIIIFeIII4 metallacrowns and strategies for optimizing the magnetocaloric effect of this topology. E. V. Salerno, J. W. Kampf, V. L. Pecoraro, T. Mallah, Inorg. Chem. Front., 2021, 8, 2611-2623
Charge transfer driven by ultrafast spin transition in a CoFe Prussian blue analogue. M. Cammarata, S. Zerdane, L. Balducci, G. Azzolina, S. Mazerat, C. Exertier, M. Trabuco, M. Levantino, R. Alonso-Mori, J. M. Glownia, S. Song, L. Catala, T. Mallah, S. F. Matar, E. Collet, Nature Chemistry, 2021, 13, 10-14
The design of magneto-plasmonic nanostructures formed by magnetic Prussian Blue-type nanocrystals decorated with Au nanoparticles. R. Sanchis-Gual, I. Susic, R. Torres-Cavanillas, D. Arenas-Esteban, S. Bals, T. Mallah, M. Coronado-Puchau, E. Coronado, Chem. Commun., 2021, 57, 1903-1906
Electrical read-out of light-induced spin transition in thin film spin crossover/graphene heterostructures. N. Konstantinov, A. Tauzin, U. N. Noumbé, D. Dragoe, B. Kundys, H. Majjad, A. Brosseau, M. Lenertz, A. Singh, S. Berciaud, M.-L. Boillot, B. Doudin, T. Mallah, J.-F. Dayen, J. Mater. Chem. C, 2021, 9, 2712-2720
Chemical tuning of spin clock transitions in molecular monomers based on nuclear spin-free Ni(ii). M. Rubín-Osanz, F. Lambert, F. Shao, E. Rivière, R. Guillot, N. Suaud, N. Guihéry, D. Zueco, A.-L. Barra, T. Mallah, F. Luis, Chem. Sci., 2021, 12, 5123-5133
Playing with Magnetic Anisotropy in Hexacoordinated Mononuclear Ni(II) Complexes, An Interplay Between Symmetry and Geometry. N. Suaud, G. Rogez, J.-N. Rebilly, M.-A. Bouammali, N. Guihéry, A.-L. Barra, T. Mallah, Applied Magnetic Resonance, 2020, 59, 13341-13346
Photoswitchable 11 nm CsCoFe Prussian Blue Analogue Nanocrystals with High Relaxation Temperature. L. Trinh, S. Zerdane, S. Mazérat, N. Dia, D. Dragoe, C. Herrero, E. Rivière, L. Catala, M. Cammarata, E. Collet, T. Mallah, Inorg. Chem., 2020, 59, 13153-13161
Long-range electron transport in Prussian blue analog nanocrystals. R. Bonnet, S. Lenfant, S. Mazérat, T. Mallah, D. Vuillaume, Nanoscale, 2020, 12, 20374-20385
Anomalous Light-Induced Spin-State Switching for Iron(II) Spin-Crossover Molecules in Direct Contact with Metal Surfaces. L. Zhang, Y. Tong, M. Kelai, A. Bellec, J. Lagoute, C. Chacon, Y. Girard, S. Rousset, M.-L. Boillot, E. Rivière, T. Mallah, E. Otero, M.-A. Arrio, P. Sainctavit, V. Repain, Angewandte Chemie International Edition, 2020, 59, 13341-13346
Coupling Nanostructured CsNiCr Prussian Blue Analogue to Resonant Microwave Fields. A. Ghirri, C. Herrero, S. Mazérat, T. Mallah, O. Moze, M. Affronte, Advanced Quantum Technologies, 2020, 3, 1900101
Magnetic relaxation studies in trigonal bipyramidal cobalt(II) complexes. F. Shao, B. Cahier, Y.-T. Wang, F.-L. Yang, E. Rivière, R. Guillot, N. Guiheŕy, J.-P. Tong, T. Mallah, Chemistry – An Asian Journal, 2020, 15, 391-397
Derivation of Lanthanide Series Crystal Field Parameters From First Principles. J. Jung, M. A. Islam, V. L. Pecoraro, T. Mallah, C. Berthon, H. Bolvin, Chemistry – A European Journal, 2019, 25, 15112-15122
Tuning bimetallic catalysts for a selective growth of SWCNTs. S. Forel, A. Castan, H. Amara, I. Florea, F. Fossard, L. Catala, C. Bichara, T. Mallah, V. Huc, A. Loiseau, C.-S. Cojocaru, Nanoscale, 2019, 11, 4091-4100
Electronic and spin delocalization in a switchable trinuclear triphenylene trisemiquinone bridged Ni3 complex. Y. Wang, F. Lambert, E. Rivière, R. Guillot, C. Herrero, A. Tissot, Z. Halime, T. Mallah, Chem. Commun., 2019, 55, 12336-12339
Influence of a Counteranion on the Zero-Field Splitting of Tetrahedral Cobalt(II) Thiourea Complexes. S. Tripathi, S. Vaidya, K. U. Ansari, N. Ahmed, E. Rivière, L. Spillecke, C. Koo, R. Klingeler, T. Mallah, G. Rajaraman, M. Shanmugam, Inorg. Chem., 2019, 58, 9085-9100
Importance of Epitaxial Strain at a Spin-Crossover Molecule–Metal Interface. C. Fourmental, S. Mondal, R. Banerjee, A. Bellec, Y. Garreau, A. Coati, C. Chacon, Y. Girard, J. Lagoute, S. Rousset, M.-L. Boillot, T. Mallah, C. Enachescu, C. Barreteau, Y. J. Dappe, A. Smogunov, S. Narasimhan, V. Repain, J. Phys. Chem. Lett., 2019, 4103-4109
Surfaces, thin films and patterning of spin crossover compounds. T. Mallah, M. Cavallini, Comptes Rendus Chimie, 2018, 21, 1270-1286
Substituted versus Naked Thiourea Ligand Containing Pseudotetrahedral Cobalt(II) Complexes: A Comparative Study on Its Magnetization Relaxation Dynamics Phenomenon. S. Vaidya, P. Shukla, S. Tripathi, E. Rivière, T. Mallah, G. Rajaraman, M. Shanmugam, Inorg. Chem., 2018, 57, 3371-3386
A Bis-Binuclear NiII Complex with Easy and Hard Axes of Magnetization: Complementary Experimental and Theoretical Insights. F. El-Khatib, B. Cahier, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, N. Guihéry, T. Mallah, European Journal of Inorganic Chemistry, 2018, 2018, 469-476
Probing Transient Photoinduced Charge Transfer in Prussian Blue Analogues with Time-Resolved XANES and Optical Spectroscopy. S. Zerdane, M. Cammarata, L. Balducci, R. Bertoni, L. Catala, S. Mazerat, T. Mallah, M. N. Pedersen, M. Wulff, K. Nakagawa, H. Tokoro, S.-I. Ohkoshi, E. Collet, European Journal of Inorganic Chemistry, 2018, 2018, 272-277
Temperature-, Light-, and Soft X-ray-Induced Spin Crossover in a Single Layer of FeII-Pyrazolylborate Molecules in Direct Contact with Gold. K. Bairagi, A. Bellec, C. Fourmental, O. Iasco, J. Lagoute, C. Chacon, Y. Girard, S. Rousset, F. Choueikani, E. Otero, P. Ohresser, P. Sainctavit, M.-L. Boillot, T. Mallah, V. Repain, J. Phys. Chem. C, 2018, 122, 727-731
Hysteresis in a bimetallic holmium complex: A synergy between electronic and nuclear magnetic interactions. M. Viciano-Chumillas, F. Koprowiak, I. Mutikainen, W. Wernsdorfer, T. Mallah, H. Bolvin, Physical Review B, 2017, 96, 214427
New method for the growth of single-walled carbon nanotubes from bimetallic nanoalloy catalysts based on Prussian blue analog precursors. A. Castan, S. Forel, L. Catala, I. Florea, F. Fossard, F. Bouanis, A. Andrieux-Ledier, S. Mazerat, T. Mallah, V. Huc, A. Loiseau, C. Sorin-Cojocaru, Carbon, 2017, 123, 583-592
The disentangling of hysteretic spin transition, polymorphism and metastability in bistable thin films formed by sublimation of bis(scorpionate) Fe(ii) molecules. O. Iasco, M.-L. Boillot, A. Bellec, R. Guillot, E. Riviere, S. Mazerat, S. Nowak, D. Morineau, A. Brosseau, F. Miserque, V. Repain, T. Mallah, J. Mater. Chem. C, 2017, 5, 11067-11075
A bird's eye view on the flat and conic band world of the honeycomb and Kagome lattices: towards an understanding of 2D metal-organic frameworks electronic structure. C. Barreteau, F. Ducastelle, T. Mallah, Journal of Physics: Condensed Matter, 2017, 29, 465302
Nanoparticles of Prussian blue analogs and related coordination polymers: From information storage to biomedical applications. L. Catala, T. Mallah, Coordination Chemistry Reviews, 2017, 346, 32-61
Design of a Binuclear Ni(II) Complex with Large Ising-type Anisotropy and Weak Anti-Ferromagnetic Coupling. F. El-Khatib, B. Cahier, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, J.-J. Girerd, N. Guihéry, T. Mallah, Inorg. Chem., 2017, 56, 10655−10663
Individual-collective crossover driven by particle size in dense assemblies of superparamagnetic nanoparticles. K. Ridier, B. Gillon, G. Chaboussant, L. Catala, S. Mazérat, E. Rivière, T. Mallah, European Physical Journal B, 2017, 90, 77
Design and Magnetic Properties of a Mononuclear Co(II) Single Molecule Magnet and Its Antiferromagnetically Coupled Binuclear Derivative. F. El-Khatib, B. Cahier, F. Shao, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, J.-J. Girerd, N. Guihéry, T. Mallah, Inorganic Chemistry, 2017, 56 (8), 4602–4609
Structural Dependence of the Ising-type Magnetic Anisotropy and of the Relaxation Time in Mononuclear Trigonal Bipyramidal Co(II) Single Molecule Magnets. F. Shao, B. Cahier, E. Rivière, R. Guillot, N. Guihéry, V. E. Campbell, T. Mallah, Inorg. Chem., 2017, 56, 1104-1111
Magnetic Anisotropy in Pentacoordinate Ni(II) and Co(II) Complexes: Unraveling Electronic and Geometrical Contributions. T. Mallah, B. Cahier, M. Perfetti, G. Zakhia, D. Naoufal, F. El-Khatib, R. Guillot, E. Rivière, R. Sessoli, A.-L. Barra, N. Guihéry, Chemistry – A European Journal, 2017, 23, 3648-3657
Engineering the magnetic coupling and anisotropy at the molecule–magnetic surface interface in molecular spintronic devices. V. E. Campbell, M. Tonelli, I. Cimatti, J.-B. Moussy, L. Tortech, Y. J. Dappe, E. Rivière, R. Guillot, S. Delprat, R. Mattana, P. Seneor, P. Ohresser, F. Choueikani, E. Otero, F. Koprowiak, V. G. Chilkuri, N. Suaud, N. Guihéry, A. Galtayries, F. Miserque, M.-A. Arrio, P. Sainctavit, T. Mallah, Nature Communications, 2016, 7, 13646
Synthesis and Magnetic Characterization of Fe(III)-Based 9-Metallacrown-3 Complexes Which Exhibit Magnetorefrigerant Properties. C. Y. Chow, R. Guillot, E. Rivière, J. W. Kampf, T. Mallah, V. L. Pecoraro, Inorg. Chem., 2016, 55, 10238-10247
Unraveling σ and π Effects on Magnetic Anisotropy in cis-NiA4B2 Complexes: Magnetization, HF-HFEPR Studies, First-Principles Calculations, and Orbital Modeling. G. Charron, E. Malkin, G. Rogez, L. J. Batchelor, S. Mazerat, R. Guillot, N. Guihéry, A.-L. Barra, T. Mallah, H. Bolvin, Chemistry – A European Journal, 2016, Volume 22, Issue 47, 16850–16862
Tools for Predicting the Nature and Magnitude of Magnetic Anisotropy in Transition Metal Complexes: Application to Co(II) Complexes. B. Cahier, R. Maurice, H. Bolvin, T. Mallah, N. Guihéry, Magnetochemistry, 2016, 2, 31
Molecular-scale dynamics of light-induced spin cross-over in a two-dimensional layer. K. Bairagi, O. Iasco, A. Bellec, A. Kartsev, D. Li, J. Lagoute, C. Chacon, Y. Girard, S. Rousset, F. Miserque, Y. J. Dappe, A. Smogunov, C. Barreteau, M.-L. Boillot, T. Mallah, V. Repain, Nat Commun, 2016, 7, 12212
Single-Molecule Magnet Behavior of Individual Polyoxometalate Molecules Incorporated within Biopolymer or Metal–Organic Framework Matrices. W. Salomon, Y. Lan, E. Rivière, S. Yang, C. Roch-Marchal, A. Dolbecq, C. Simonnet-Jégat, N. Steunou, N. Leclerc-Laronze, L. Ruhlmann, T. Mallah, W. Wernsdorfer, P. Mialane, Chemistry – A European Journal, 2016, 22, 6564-6574
Synthesis, X-ray structure and catecholase activity of an antiferromagnetically coupled trinuclear nickel(II) complex. A. Pal, S. C. Kumar, A. K. Ghosh, C.-H. Lin, E. Rivière, T. Mallah, R. Ghosh, Polyhedron, 2016, 110, 221-226
Small-angle neutron scattering study of the short-range organization of dispersed CsNi[Cr(CN)6] nanoparticles. K. Ridier, B. Gillon, G. André, G. Chaboussant, L. Catala, S. Mazérat, T. Mallah, Journal of Applied Physics, 2015, 118, 114304
Assessing the exchange coupling in binuclear lanthanide(iii) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy2 derivative. C. Y. Chow, H. Bolvin, V. E. Campbell, R. Guillot, J. W. Kampf, W. Wernsdorfer, F. Gendron, J. Autschbach, V. L. Pecoraro, T. Mallah, Chem. Sci., 2015, 6, 4148-4159
Tuning the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes. F. Shao, B. Cahier, N. Guihéry, E. Rivière, R. Guillot, A.-L. Barra, Y. Lan, W. Wernsdorfer, V. E. Campbell, T. Mallah, Chem. Commun., 2015, 51, 16475-16478
Imaging the Magnetic Reversal of Isolated and Organized Molecular-Based Nanoparticles using Magnetic Force Microscopy. E. Pinilla-Cienfuegos, S. Kumar, S. Mañas-Valero, J. Canet-Ferrer, L. Catala, T. Mallah, A. Forment-Aliaga, E. Coronado, Particle & Particle Systems Characterization, 2015, 32, 693-700
Direct Synthesis and Integration of Individual, Diameter-Controlled Single-Walled Nanotubes (SWNTs). F. Z. Bouanis, C. S. Cojocaru, V. Huc, E. Norman, M. Chaigneau, J.-L. Maurice, T. Mallah, D. Pribat, Chem. Mater., 2014, 26, 5074-5082
Tailoring the Structure of Two-Dimensional Self-Assembled Nanoarchitectures Based on NiII–Salen Building Blocks. M. Viciano-Chumillas, D. Li, A. Smogunov, S. Latil, Y. J. Dappe, C. Barreteau, T. Mallah, F. Silly, Chemistry – A European Journal, 2014, 20, 13566-13575
Magnetization Reversal in CsNiIICrIII(CN)6 Coordination Nanoparticles: Unravelling Surface Anisotropy and Dipolar Interaction Effects. Y. Prado, S. Mazerat, E. Rivière, G. Rogez, A. Gloter, O. Stéphan, L. Catala, T. Mallah, Advanced Functional Materials, 2014, 24, 5402-5411
MnII-containing coordination nanoparticles as highly efficient T1 contrast agents for magnetic resonance imaging. G. Paul, Y. Prado, N. Dia, E. Riviere, S. Laurent, M. Roch, L. V. Elst, R. N. Muller, L. Sancey, P. Perriat, O. Tillement, T. Mallah, L. Catala, Chemical Communications, 2014, 50, 6740-6743
Understanding Spin Structure in Metallacrown Single-Molecule Magnets using Magnetic Compton Scattering. A. Deb, T. T. Boron, M. Itou, Y. Sakurai, T. Mallah, V. L. Pecoraro, J. E. Penner-Hahn, Journal of the American Chemical Society, 2014, 136, 4889-4892
Assembly of heterobimetallic NiII-LnIII (LnIII = DyIII, TbIII, GdIII, HoIII, ErIII, YIII) complexes using a ferrocene ligand: slow relaxation of the magnetization in DyIII, TbIII and HoIII analogues. A. Chakraborty, P. Bag, E. Riviere, T. Mallah, V. Chandrasekhar, Dalton Transactions, 2014, 43, 8921-8932
Structural and Electronic Dependence of the Single-Molecule-Magnet Behavior of Dysprosium(III) Complexes. V. E. Campbell, H. Bolvin, E. Rivière, R. Guillot, W. Wernsdorfer, T. Mallah, Inorganic Chemistry, 2014, 53, 2598-2605
Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes. L. J. Batchelor, I. Cimatti, R. Guillot, F. Tuna, W. Wernsdorfer, L. Ungur, L. F. Chibotaru, V. E. Campbell, T. Mallah, Dalton Trans., 2014, 43, 12146-12149
Ising-type magnetic anisotropy and single molecule magnet behaviour in mononuclear trigonal bipyramidal Co(ii) complexes. R. Ruamps, L. J. Batchelor, R. Guillot, G. Zakhia, A.-L. Barra, W. Wernsdorfer, N. Guihery, T. Mallah, Chem. Sci., 2014, 5, 3418-3424