Institut de Chimie Moléculaire et des Matériaux d'Orsay

Talal Mallah

Bât. 670, bureau 2227 – LCI – ICMMO - UMR 8182
Université Paris-Saclay
Bâtiment 670
17-19 Avenue des Sciences
91400 Orsay

+33 1 69 15 47 55

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Detection of a Jahn–Teller mode as an ultrafast fingerprint of spin-transition-induced charge transfer in CoFe Prussian Blue Analogue. M. Hervé, B. Marekha, S. Mazerat, T. Mallah, M. Cammarata, S. F. Matar, S. Haacke, J. Léonard, E. Collet, Mater. Adv., 2024

Understanding the Electronic Structure of Magnetic Trinuclear Complexes Based on the Tris-dioxolene Triphenylene Non-innocent Bridging Ligand, a Theoretical Study. N. Suaud, A. Colin, M. Bouammali, T. Mallah, N. Guihéry, Chemistry – A European Journal, 2023, n/a, e202302256

Optical Read-Out of the Electrical Switching of Cobalt-Terpyridine-BODIPY Molecules Immobilized as Single Layer on ITO. K. Magra, J.-F. Audibert, D. Dragoe, T. Mallah, F. Miomandre, M.-L. Boillot, Advanced Optical Materials, 2023, 11, 2301128

Mechanoelastic simulations of monolayer lattices of spin crossover molecules on a substrate. A. Railean, M. Kelai, A. Bellec, V. Repain, M.-L. Boillot, T. Mallah, L. Stoleriu, C. Enachescu, Physical Review B, 2023, 107, 014304

Hybrid nanostructures based on gold nanoparticles and functional coordination polymers: Chemistry, physics and applications in biomedicine, catalysis and magnetism. R. Sanchis-Gual, M. Coronado-Puchau, T. Mallah, E. Coronado, Coordination Chemistry Reviews, 2023, 480, 215025

Interface versus Bulk Light-Induced Switching in Spin-Crossover Molecular Ultrathin Films Adsorbed on a Metallic Surface. M. Kelai, A. Tauzin, A. Railean, V. Repain, J. Lagoute, Y. Girard, S. Rousset, E. Otero, T. Mallah, M.-L. Boillot, C. Enachescu, A. Bellec, J. Phys. Chem. Lett., 2023, 14, 1949-1954

Unique Dimerization Topology and Countercation Binding Modes in 12-Metallacrown-4 Compounds. E. V. Salerno, C. M. Foley, V. Marzaroli, B. L. Schneider, M. D. Sharin, J. W. Kampf, L. Marchiò, M. Zeller, R. Guillot, T. Mallah, M. Tegoni, V. L. Pecoraro, C. M. Zaleski, European Journal of Inorganic Chemistry, 2022, 2022, e202200439

Out-of-equilibrium dynamics driven by photoinduced charge transfer in CsCoFe Prussian blue analogue nanocrystals. S. Zerdane, M. Hervé, S. Mazerat, L. Catala, R. Alonso-Mori, J. M. Glownia, S. Song, M. Levantino, T. Mallah, M. Cammarata, E. Collet, Faraday Discuss., 2022

XAS and XMCD Reveal a Cobalt(II) Imide Undergoes High-Pressure-Induced Spin Crossover. N. Bouldi, M. Mannini, M. Retegan, R. G. Miller, B. Cahier, P. Sainctavit, N. Guihéry, T. Mallah, D. Cabaret, D. Gouéré, F. Baudelet, L. Nataf, F. Wilhelm, F. Guillou, A. Rogalev, N. Suaud, S. Brooker, A. Juhin, J. Phys. Chem. C, 2022, 126, 5784-5792

Terphenylthiazole-based self-assembled monolayers on cobalt with high conductance photo-switching ratio for spintronics. V. Prudkovskiy, I. Arbouch, A. Léaustic, P. Yu, C. Van Dyck, D. Guérin, S. Lenfant, T. Mallah, J. Cornil, D. Vuillaume, Nanoscale, 2022, 14, 5725-5742

Robust magnetic anisotropy of a monolayer of hexacoordinate Fe(ii) complexes assembled on Cu(111). M. Kelai, B. Cahier, M. Atanasov, F. Neese, Y. Tong, L. Zhang, A. Bellec, O. Iasco, E. Rivière, R. Guillot, C. Chacon, Y. Girard, J. Lagoute, S. Rousset, V. Repain, E. Otero, M.-A. Arrio, P. Sainctavit, A.-L. Barra, M.-L. Boillot, T. Mallah, Inorg. Chem. Front., 2021, 8, 2395-2404

Voltage-Induced Bistability of Single Spin-Crossover Molecules in a Two-Dimensional Monolayer. Y. Tong, M. Kelaï, K. Bairagi, V. Repain, J. Lagoute, Y. Girard, S. Rousset, M.-L. Boillot, T. Mallah, C. Enachescu, A. Bellec, J. Phys. Chem. Lett., 2021, 12, 11029-11034

Magnetic Hysteresis in a Monolayer of Oriented 6 nm CsNiCr Prussian Blue Analogue Nanocrystals. L. Zhang, M.-A. Arrio, S. Mazerat, L. Catala, W. Li, E. Otero, P. Ohresser, L. Lisnard, C. Cartier Dit Moulin, T. Mallah, P. Sainctavit, Inorg. Chem., 2021, 60, 16388-16396

A high-frequency EPR study of magnetic anisotropy and intermolecular interactions of Co(II) ions. L. Spillecke, S. Tripathi, C. Koo, M. Ansari, S. Vaidya, A. Rasamsetty, T. Mallah, G. Rajaraman, M. Shanmugam, R. Klingeler, Polyhedron, 2021, 208, 115389

Collective Magnetic Behavior of 11 nm Photo-Switchable CsCoFe Prussian Blue Analogue Nanocrystals: Effect of Dilution and Light Intensity. L. Trinh, E. Rivière, S. Mazerat, L. Catala, T. Mallah, Magnetochemistry, 2021, 7

Thermal Bistability of an Ultrathin Film of Iron(II) Spin-Crossover Molecules Directly Adsorbed on a Metal Surface. M. Kelai, V. Repain, A. Tauzin, W. Li, Y. Girard, J. Lagoute, S. Rousset, E. Otero, P. Sainctavit, M.-A. Arrio, M.-L. Boillot, T. Mallah, C. Enachescu, A. Bellec, J. Phys. Chem. Lett., 2021, 12, 6152-6158

Magnetic properties of two GdIIIFeIII4 metallacrowns and strategies for optimizing the magnetocaloric effect of this topology. E. V. Salerno, J. W. Kampf, V. L. Pecoraro, T. Mallah, Inorg. Chem. Front., 2021, 8, 2611-2623

Charge transfer driven by ultrafast spin transition in a CoFe Prussian blue analogue. M. Cammarata, S. Zerdane, L. Balducci, G. Azzolina, S. Mazerat, C. Exertier, M. Trabuco, M. Levantino, R. Alonso-Mori, J. M. Glownia, S. Song, L. Catala, T. Mallah, S. F. Matar, E. Collet, Nature Chemistry, 2021, 13, 10-14

The design of magneto-plasmonic nanostructures formed by magnetic Prussian Blue-type nanocrystals decorated with Au nanoparticles. R. Sanchis-Gual, I. Susic, R. Torres-Cavanillas, D. Arenas-Esteban, S. Bals, T. Mallah, M. Coronado-Puchau, E. Coronado, Chem. Commun., 2021, 57, 1903-1906

Electrical read-out of light-induced spin transition in thin film spin crossover/graphene heterostructures. N. Konstantinov, A. Tauzin, U. N. Noumbé, D. Dragoe, B. Kundys, H. Majjad, A. Brosseau, M. Lenertz, A. Singh, S. Berciaud, M.-L. Boillot, B. Doudin, T. Mallah, J.-F. Dayen, J. Mater. Chem. C, 2021, 9, 2712-2720

Chemical tuning of spin clock transitions in molecular monomers based on nuclear spin-free Ni(ii). M. Rubín-Osanz, F. Lambert, F. Shao, E. Rivière, R. Guillot, N. Suaud, N. Guihéry, D. Zueco, A.-L. Barra, T. Mallah, F. Luis, Chem. Sci., 2021, 12, 5123-5133

Playing with Magnetic Anisotropy in Hexacoordinated Mononuclear Ni(II) Complexes, An Interplay Between Symmetry and Geometry. N. Suaud, G. Rogez, J.-N. Rebilly, M.-A. Bouammali, N. Guihéry, A.-L. Barra, T. Mallah, Applied Magnetic Resonance, 2020, 59, 13341-13346

Photoswitchable 11 nm CsCoFe Prussian Blue Analogue Nanocrystals with High Relaxation Temperature. L. Trinh, S. Zerdane, S. Mazérat, N. Dia, D. Dragoe, C. Herrero, E. Rivière, L. Catala, M. Cammarata, E. Collet, T. Mallah, Inorg. Chem., 2020, 59, 13153-13161

Long-range electron transport in Prussian blue analog nanocrystals. R. Bonnet, S. Lenfant, S. Mazérat, T. Mallah, D. Vuillaume, Nanoscale, 2020, 12, 20374-20385

Anomalous Light-Induced Spin-State Switching for Iron(II) Spin-Crossover Molecules in Direct Contact with Metal Surfaces. L. Zhang, Y. Tong, M. Kelai, A. Bellec, J. Lagoute, C. Chacon, Y. Girard, S. Rousset, M.-L. Boillot, E. Rivière, T. Mallah, E. Otero, M.-A. Arrio, P. Sainctavit, V. Repain, Angewandte Chemie International Edition, 2020, 59, 13341-13346

Coupling Nanostructured CsNiCr Prussian Blue Analogue to Resonant Microwave Fields. A. Ghirri, C. Herrero, S. Mazérat, T. Mallah, O. Moze, M. Affronte, Advanced Quantum Technologies, 2020, 3, 1900101

Magnetic relaxation studies in trigonal bipyramidal cobalt(II) complexes. F. Shao, B. Cahier, Y.-T. Wang, F.-L. Yang, E. Rivière, R. Guillot, N. Guiheŕy, J.-P. Tong, T. Mallah, Chemistry – An Asian Journal, 2020, 15, 391-397

Derivation of Lanthanide Series Crystal Field Parameters From First Principles. J. Jung, M. A. Islam, V. L. Pecoraro, T. Mallah, C. Berthon, H. Bolvin, Chemistry – A European Journal, 2019, 25, 15112-15122

Tuning bimetallic catalysts for a selective growth of SWCNTs. S. Forel, A. Castan, H. Amara, I. Florea, F. Fossard, L. Catala, C. Bichara, T. Mallah, V. Huc, A. Loiseau, C.-S. Cojocaru, Nanoscale, 2019, 11, 4091-4100

Electronic and spin delocalization in a switchable trinuclear triphenylene trisemiquinone bridged Ni3 complex. Y. Wang, F. Lambert, E. Rivière, R. Guillot, C. Herrero, A. Tissot, Z. Halime, T. Mallah, Chem. Commun., 2019, 55, 12336-12339

Influence of a Counteranion on the Zero-Field Splitting of Tetrahedral Cobalt(II) Thiourea Complexes. S. Tripathi, S. Vaidya, K. U. Ansari, N. Ahmed, E. Rivière, L. Spillecke, C. Koo, R. Klingeler, T. Mallah, G. Rajaraman, M. Shanmugam, Inorg. Chem., 2019, 58, 9085-9100

Importance of Epitaxial Strain at a Spin-Crossover Molecule–Metal Interface. C. Fourmental, S. Mondal, R. Banerjee, A. Bellec, Y. Garreau, A. Coati, C. Chacon, Y. Girard, J. Lagoute, S. Rousset, M.-L. Boillot, T. Mallah, C. Enachescu, C. Barreteau, Y. J. Dappe, A. Smogunov, S. Narasimhan, V. Repain, J. Phys. Chem. Lett., 2019, 4103-4109

Surfaces, thin films and patterning of spin crossover compounds. T. Mallah, M. Cavallini, Comptes Rendus Chimie, 2018, 21, 1270-1286

Substituted versus Naked Thiourea Ligand Containing Pseudotetrahedral Cobalt(II) Complexes: A Comparative Study on Its Magnetization Relaxation Dynamics Phenomenon. S. Vaidya, P. Shukla, S. Tripathi, E. Rivière, T. Mallah, G. Rajaraman, M. Shanmugam, Inorg. Chem., 2018, 57, 3371-3386

A Bis-Binuclear NiII Complex with Easy and Hard Axes of Magnetization: Complementary Experimental and Theoretical Insights. F. El-Khatib, B. Cahier, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, N. Guihéry, T. Mallah, European Journal of Inorganic Chemistry, 2018, 2018, 469-476

Probing Transient Photoinduced Charge Transfer in Prussian Blue Analogues with Time-Resolved XANES and Optical Spectroscopy. S. Zerdane, M. Cammarata, L. Balducci, R. Bertoni, L. Catala, S. Mazerat, T. Mallah, M. N. Pedersen, M. Wulff, K. Nakagawa, H. Tokoro, S.-I. Ohkoshi, E. Collet, European Journal of Inorganic Chemistry, 2018, 2018, 272-277

Temperature-, Light-, and Soft X-ray-Induced Spin Crossover in a Single Layer of FeII-Pyrazolylborate Molecules in Direct Contact with Gold. K. Bairagi, A. Bellec, C. Fourmental, O. Iasco, J. Lagoute, C. Chacon, Y. Girard, S. Rousset, F. Choueikani, E. Otero, P. Ohresser, P. Sainctavit, M.-L. Boillot, T. Mallah, V. Repain, J. Phys. Chem. C, 2018, 122, 727-731

Hysteresis in a bimetallic holmium complex: A synergy between electronic and nuclear magnetic interactions. M. Viciano-Chumillas, F. Koprowiak, I. Mutikainen, W. Wernsdorfer, T. Mallah, H. Bolvin, Physical Review B, 2017, 96, 214427

New method for the growth of single-walled carbon nanotubes from bimetallic nanoalloy catalysts based on Prussian blue analog precursors. A. Castan, S. Forel, L. Catala, I. Florea, F. Fossard, F. Bouanis, A. Andrieux-Ledier, S. Mazerat, T. Mallah, V. Huc, A. Loiseau, C. Sorin-Cojocaru, Carbon, 2017, 123, 583-592

The disentangling of hysteretic spin transition, polymorphism and metastability in bistable thin films formed by sublimation of bis(scorpionate) Fe(ii) molecules. O. Iasco, M.-L. Boillot, A. Bellec, R. Guillot, E. Riviere, S. Mazerat, S. Nowak, D. Morineau, A. Brosseau, F. Miserque, V. Repain, T. Mallah, J. Mater. Chem. C, 2017, 5, 11067-11075

A bird's eye view on the flat and conic band world of the honeycomb and Kagome lattices: towards an understanding of 2D metal-organic frameworks electronic structure. C. Barreteau, F. Ducastelle, T. Mallah, Journal of Physics: Condensed Matter, 2017, 29, 465302

Nanoparticles of Prussian blue analogs and related coordination polymers: From information storage to biomedical applications. L. Catala, T. Mallah, Coordination Chemistry Reviews, 2017, 346, 32-61

Design of a Binuclear Ni(II) Complex with Large Ising-type Anisotropy and Weak Anti-Ferromagnetic Coupling. F. El-Khatib, B. Cahier, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, J.-J. Girerd, N. Guihéry, T. Mallah, Inorg. Chem., 2017, 56, 10655−10663

Individual-collective crossover driven by particle size in dense assemblies of superparamagnetic nanoparticles. K. Ridier, B. Gillon, G. Chaboussant, L. Catala, S. Mazérat, E. Rivière, T. Mallah, European Physical Journal B, 2017, 90, 77

Design and Magnetic Properties of a Mononuclear Co(II) Single Molecule Magnet and Its Antiferromagnetically Coupled Binuclear Derivative. F. El-Khatib, B. Cahier, F. Shao, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, J.-J. Girerd, N. Guihéry, T. Mallah, Inorganic Chemistry, 2017, 56 (8), 4602–4609

Structural Dependence of the Ising-type Magnetic Anisotropy and of the Relaxation Time in Mononuclear Trigonal Bipyramidal Co(II) Single Molecule Magnets. F. Shao, B. Cahier, E. Rivière, R. Guillot, N. Guihéry, V. E. Campbell, T. Mallah, Inorg. Chem., 2017, 56, 1104-1111

Magnetic Anisotropy in Pentacoordinate Ni(II) and Co(II) Complexes: Unraveling Electronic and Geometrical Contributions. T. Mallah, B. Cahier, M. Perfetti, G. Zakhia, D. Naoufal, F. El-Khatib, R. Guillot, E. Rivière, R. Sessoli, A.-L. Barra, N. Guihéry, Chemistry – A European Journal, 2017, 23, 3648-3657

Engineering the magnetic coupling and anisotropy at the molecule–magnetic surface interface in molecular spintronic devices. V. E. Campbell, M. Tonelli, I. Cimatti, J.-B. Moussy, L. Tortech, Y. J. Dappe, E. Rivière, R. Guillot, S. Delprat, R. Mattana, P. Seneor, P. Ohresser, F. Choueikani, E. Otero, F. Koprowiak, V. G. Chilkuri, N. Suaud, N. Guihéry, A. Galtayries, F. Miserque, M.-A. Arrio, P. Sainctavit, T. Mallah, Nature Communications, 2016, 7, 13646

Synthesis and Magnetic Characterization of Fe(III)-Based 9-Metallacrown-3 Complexes Which Exhibit Magnetorefrigerant Properties. C. Y. Chow, R. Guillot, E. Rivière, J. W. Kampf, T. Mallah, V. L. Pecoraro, Inorg. Chem., 2016, 55, 10238-10247

Unraveling σ and π Effects on Magnetic Anisotropy in cis-NiA4B2 Complexes: Magnetization, HF-HFEPR Studies, First-Principles Calculations, and Orbital Modeling. G. Charron, E. Malkin, G. Rogez, L. J. Batchelor, S. Mazerat, R. Guillot, N. Guihéry, A.-L. Barra, T. Mallah, H. Bolvin, Chemistry – A European Journal, 2016, Volume 22, Issue 47, 16850–16862

Tools for Predicting the Nature and Magnitude of Magnetic Anisotropy in Transition Metal Complexes: Application to Co(II) Complexes. B. Cahier, R. Maurice, H. Bolvin, T. Mallah, N. Guihéry, Magnetochemistry, 2016, 2, 31

Molecular-scale dynamics of light-induced spin cross-over in a two-dimensional layer. K. Bairagi, O. Iasco, A. Bellec, A. Kartsev, D. Li, J. Lagoute, C. Chacon, Y. Girard, S. Rousset, F. Miserque, Y. J. Dappe, A. Smogunov, C. Barreteau, M.-L. Boillot, T. Mallah, V. Repain, Nat Commun, 2016, 7, 12212

Single-Molecule Magnet Behavior of Individual Polyoxometalate Molecules Incorporated within Biopolymer or Metal–Organic Framework Matrices. W. Salomon, Y. Lan, E. Rivière, S. Yang, C. Roch-Marchal, A. Dolbecq, C. Simonnet-Jégat, N. Steunou, N. Leclerc-Laronze, L. Ruhlmann, T. Mallah, W. Wernsdorfer, P. Mialane, Chemistry – A European Journal, 2016, 22, 6564-6574

Synthesis, X-ray structure and catecholase activity of an antiferromagnetically coupled trinuclear nickel(II) complex. A. Pal, S. C. Kumar, A. K. Ghosh, C.-H. Lin, E. Rivière, T. Mallah, R. Ghosh, Polyhedron, 2016, 110, 221-226

Small-angle neutron scattering study of the short-range organization of dispersed CsNi[Cr(CN)6] nanoparticles. K. Ridier, B. Gillon, G. André, G. Chaboussant, L. Catala, S. Mazérat, T. Mallah, Journal of Applied Physics, 2015, 118, 114304

Assessing the exchange coupling in binuclear lanthanide(iii) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy2 derivative. C. Y. Chow, H. Bolvin, V. E. Campbell, R. Guillot, J. W. Kampf, W. Wernsdorfer, F. Gendron, J. Autschbach, V. L. Pecoraro, T. Mallah, Chem. Sci., 2015, 6, 4148-4159

Tuning the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes. F. Shao, B. Cahier, N. Guihéry, E. Rivière, R. Guillot, A.-L. Barra, Y. Lan, W. Wernsdorfer, V. E. Campbell, T. Mallah, Chem. Commun., 2015, 51, 16475-16478

Imaging the Magnetic Reversal of Isolated and Organized Molecular-Based Nanoparticles using Magnetic Force Microscopy. E. Pinilla-Cienfuegos, S. Kumar, S. Mañas-Valero, J. Canet-Ferrer, L. Catala, T. Mallah, A. Forment-Aliaga, E. Coronado, Particle & Particle Systems Characterization, 2015, 32, 693-700

Direct Synthesis and Integration of Individual, Diameter-Controlled Single-Walled Nanotubes (SWNTs). F. Z. Bouanis, C. S. Cojocaru, V. Huc, E. Norman, M. Chaigneau, J.-L. Maurice, T. Mallah, D. Pribat, Chem. Mater., 2014, 26, 5074-5082

Tailoring the Structure of Two-Dimensional Self-Assembled Nanoarchitectures Based on NiII–Salen Building Blocks. M. Viciano-Chumillas, D. Li, A. Smogunov, S. Latil, Y. J. Dappe, C. Barreteau, T. Mallah, F. Silly, Chemistry – A European Journal, 2014, 20, 13566-13575

Magnetization Reversal in CsNiIICrIII(CN)6 Coordination Nanoparticles: Unravelling Surface Anisotropy and Dipolar Interaction Effects. Y. Prado, S. Mazerat, E. Rivière, G. Rogez, A. Gloter, O. Stéphan, L. Catala, T. Mallah, Advanced Functional Materials, 2014, 24, 5402-5411

MnII-containing coordination nanoparticles as highly efficient T1 contrast agents for magnetic resonance imaging. G. Paul, Y. Prado, N. Dia, E. Riviere, S. Laurent, M. Roch, L. V. Elst, R. N. Muller, L. Sancey, P. Perriat, O. Tillement, T. Mallah, L. Catala, Chemical Communications, 2014, 50, 6740-6743

Understanding Spin Structure in Metallacrown Single-Molecule Magnets using Magnetic Compton Scattering. A. Deb, T. T. Boron, M. Itou, Y. Sakurai, T. Mallah, V. L. Pecoraro, J. E. Penner-Hahn, Journal of the American Chemical Society, 2014, 136, 4889-4892

Assembly of heterobimetallic NiII-LnIII (LnIII = DyIII, TbIII, GdIII, HoIII, ErIII, YIII) complexes using a ferrocene ligand: slow relaxation of the magnetization in DyIII, TbIII and HoIII analogues. A. Chakraborty, P. Bag, E. Riviere, T. Mallah, V. Chandrasekhar, Dalton Transactions, 2014, 43, 8921-8932

Structural and Electronic Dependence of the Single-Molecule-Magnet Behavior of Dysprosium(III) Complexes. V. E. Campbell, H. Bolvin, E. Rivière, R. Guillot, W. Wernsdorfer, T. Mallah, Inorganic Chemistry, 2014, 53, 2598-2605

Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes. L. J. Batchelor, I. Cimatti, R. Guillot, F. Tuna, W. Wernsdorfer, L. Ungur, L. F. Chibotaru, V. E. Campbell, T. Mallah, Dalton Trans., 2014, 43, 12146-12149

Ising-type magnetic anisotropy and single molecule magnet behaviour in mononuclear trigonal bipyramidal Co(ii) complexes. R. Ruamps, L. J. Batchelor, R. Guillot, G. Zakhia, A.-L. Barra, W. Wernsdorfer, N. Guihery, T. Mallah, Chem. Sci., 2014, 5, 3418-3424