Institut de Chimie Moléculaire et des Matériaux d'Orsay

Régis Guillot

Ingénieur de Recherche
Bât. 420 – SC – ICMMO
Université Paris-Sud
15, rue Georges Clémenceau
91405 Orsay Cedex

+33 1 69 15 47 52



Equipe de Soutient Scientifique et Technique

(plateforme instrumentale)

Responsable du service de diffraction sur mono-cristal



Localisation : Bât. 420 (Rue du doyen Georges Poitou) , RDC, Bureau 054A

Téléphone salle des diffractomètres :

Ingénieur de recherche depuis le premier décembre 2003, en charge de la création et de l’animation du service de diffraction des rayons X sur monocristal de l’ICMMO.



Formation initiale



Dernières Publications


Selective Formation of an FeIVO or an FeIIIOOH Intermediate From FeII-H2O2 : Controlled Heterolytic vs Homolytic O-O Bond Cleavage by the Second Coordination Sphere. K. Cheaib, M. Q. E. Mubarak, K. Sénéchal-David, C. Herrero, R. Guillot, M. Clémancey, J.-M. Latour, S. D. Visser, J.-P. Mahy, F. Banse, F. Avenier, Angew. Chem. Int. Ed., 2019, 58, 854-858

Mechano-responsive circularly polarized luminescence of organic solid-state chiral emitters. M. Louis, R. Sethy, J. Kumar, S. Katao, R. Guillot, T. Nakashima, C. Allain, T. Kawai, R. Metivier, Chem. Sci., 2019

Brønsted Acid Mediated Cascade Reaction to Access 3‑(2-Bromoethyl)benzofurans. S. Porcu, S. Demuro, A. Luridiana, A. Cocco, A. Frongia, D. J. Aitken, F. Charnay-Pouget, R. Guillot, G. Sarais, F. Secci, Org. Lett., 2018, 20, 7699-7702

Synthesis of Cyclopenta[b]piperazinones via an Azaoxyallyl Cation. B. Baldé, G. Force, L. Marin, R. Guillot, E. Schulz, V. Gandon, D. Lebœuf, Org. Lett., 2018, 20, 7405-7409

Interaction of Functionalized Naphthalenophanes with Abasic Sites in DNA: DNA Cleavage, DNA Cleavage Inhibition, and Formation of Ligand–DNA Adducts. C. Caron, X. N. T. Duong, R. Guillot, S. Bombard, A. Granzhan, Chemistry – A European Journal, 2018

C1-symmetric β-Diketiminatoiron(II) Complexes for Hydroamination of Primary Alkenylamines. C. Lepori, R. Guillot, J. Hannedouche, Advanced Synthesis & Catalysis, 2018, 0

Acid-catalyzed synthesis of functionalized arylthio cyclopropane carbaldehydes and ketones. S. Porcu, A. Luridiana, A. Martis, A. Frongia, G. Sarais, D. J. Aitken, T. Boddaert, R. Guillot, F. Secci, Chem. Commun., 2018, 54, 13547-13550

Experimental and computational mechanistic studies of the β-diketiminatoiron(II)-catalysed hydroamination of alkenes tethered to primary amines. C. Lepori, E. Bernoud, R. Guillot, S. Tobisch, J. Hannedouche, Chemistry – A European Journal, 2018

Oxidative Coupling of Enolates by Memory of Chirality: an Original Enantioselective Synthesis of Quaternary alpha-Amino Acid Derivatives. A. Mambrini, D. Gori, R. Guillot, C. Kouklovsky, V. Alezra, Chemical Communications, 2018, 54, 12742 - 12745

Benzyloxycalix[8]arene: a new valuable support for NHC palladium complexes in C–C Suzuki–Miyaura couplings. I. Abdellah, P. Kasongo, A. Labattut, R. Guillot, E. Schulz, C. Martini, V. Huc, Dalton Trans., 2018, 47, 13843-13848

Synthesis of 3-Substituted 3-Bromo-1-phenylallenes from Alkynylcycloheptatrienes. M. Vayer, R. Guillot, C. Bour, V. Gandon, J. Org. Chem., 2018, 83, 11309–11317

Receptor-based artificial metalloenzymes on living human cells. W. Ghattas, V. Dubosclard, A. Wick, A. Bendelac, R. Guillot, R. Ricoux, J.-P. Mahy, J. Am. Chem. Soc., 2018, 140, 8756-8762

Revealing the Origins of Mechanically Induced Fluorescence Changes in Organic Molecular Crystals. L. Wilbraham, M. Louis, D. Alberga, A. Brosseau, R. Guillot, F. Ito, F. Labat, R. Métivier, C. Allain, I. Ciofini, Advanced Materials, 2018

β-Diketone derivatives: influence of the chelating group on the photophysical and mechanofluorochromic properties. M. Louis, R. Guillot, R. Metivier, C. Allain, Photochem. Photobiol. Sci., 2018, 17, 822-828

N-Iodosuccinimide-Mediated Oxidative Coupling of Indoles and Phenols: A Synthetic Study toward the Benzofuroindoline Moiety of Bipleiophylline. N. Denizot, R. Guillot, C. Kouklovsky, G. Vincent, Synthesis, 2018, 50, 4823-4828

Well-Defined β-Diketiminatocobalt(II) Complexes for Alkene Cyclohydroamination of Primary Amines. C. Lepori, P. Gómez-Orellana, A. Ouharzoune, R. Guillot, A. Lledós, G. Ujaque, J. Hannedouche, ACS Catal., 2018, 4446-4451

Water Molecules Gating a Photoinduced One Electron Two Protons Transfer in a Tyr/His model of Photosystem II. G. Chararalambidis, S. Das, A. Trapali, A. Quaranta, M. Orio, Z. Halime, P. Fertey, R. Guillot, C. Athanassios, W. Leibl, A. Aukauloo, M. Sircoglou, Angew. Chem. Int. Ed., 2018, 57, 9013-9017

Triphenylamine–Thienothiophene Organic Charge‐Transport Molecular Materials: Effect of Substitution Pattern on their Thermal, Photoelectrochemical, and Photovoltaic Properties. T. H. Le, Q. Dao, M. Nghiêm, S. Péralta, R. Guillot, Q. N. Pham, A. Fujii, M. Ozaki, F. Goubard, T. Bui, Chemistry – An Asian Journal, 2018, 18, 1302-1311

Preparation of cyclobutene acetals and tricyclic oxetanes via photochemical tandem and cascade reactions. J. Buendia, Z. Chang, H. Eijsberg, R. Guillot, A. Frongia, F. Secci, J. Xie, S. Robin, T. Boddaert, D. J. Aitken, Angewandte Chemie International Edition, 2018, 57, 6592-6596

Diastereoselective Synthesis of an Advanced Intermediate of Thapsigargin and Other 6,12-Guaianolides Using a RCEYM Strategy. M. Jouanneau, K. R. Bonepally, A. Jeuken, A. Tap, R. Guillot, J. Ardisson, J.-P. Férézou, J. Prunet, Org. Lett., 2018, 20, 2176-2180

A Metallo Pro-Drug to Target CuII in the Context of Alzheimer's Disease. A. Conte-Daban, V. Ambike, R. Guillot, N. Delsuc, C. Policar, C. Hureau, Chemistry – A European Journal, 2018, Volume24, Issue20, 5095-5099

Dearomative Diallylation of N-Acylindoles Mediated by FeCl3. J. Wu, R. K. Nandi, R. Guillot, C. Kouklovsky, G. Vincent, Org. Lett., 2018, 20, 1845-1848

Base mediated fragmentation of bicyclic dihydro-3,6-oxazines: transformation of nitroso Diels-Alder cycloadducts. R. Campagne, F. Schäkel, R. Guillot, V. Alezra, C. Kouklovsky, Org. Lett., 2018, 20, 1884-1887

A Bis-Binuclear NiII Complex with Easy and Hard Axes of Magnetization: Complementary Experimental and Theoretical Insights. F. El-Khatib, B. Cahier, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, N. Guihéry, T. Mallah, European Journal of Inorganic Chemistry, 2018, 2018, 469-476

Cooperative 5- and 10-membered ring interactions in the 10-helix folding of oxetin homo-oligomers. S. S. Ragab, A. F. Kassir, R. Guillot, M.-C. Scherrmann, T. Boddaert, D. J. Aitken, Chem. Commun., 2018, 54, 1968-1971

A diversity-oriented synthesis of cyclopenta[b]pyrroles and related compounds through a calcium(ii)/copper(ii) catalytic sequence. L. Marin, R. Guillot, V. Gandon, E. Schulz, D. Lebœuf, Org. Chem. Front., 2018, 5, 640-647

A Photochemical Route to 3- and 4-Hydroxy Derivatives of 2-Aminocyclobutane-1-carboxylic Acid with an all-cis Geometry. Z. Chang, F. Boyaud, R. Guillot, T. Boddaert, D. J. Aitken, Journal of Organic Chemistry, 2018, 83, 527-534

Catalytic Use of Low-Valent Cationic Gallium(I) Complexes as π-Acids. Z. Li, G. Thiery, M. R. Lichtenthaler, R. Guillot, I. Krossing, V. Gandon, C. Bour, Advanced Synthesis & Catalysis, 2018, Volume360, Issue3, 544-549

Constrained cyclic beta,gamma-diamino acids from glutamic acid: synthesis of both diastereomers and unexpected kinetic resolution. V. Alezra, Y. Wan, N. Auberger, S. Thétiot-Laurent, F. Bouillère, A. Zulauf, J. He, S. Courtiol-Legourd, R. Guillot, C. Kouklovsky, S. Cote Des Combes, C. Pacaud, I. Devillers, Eur. J. Org. Chem., 2018, 329-340

Triflic acid as an efficient Brønsted acid promoter for the Umpolung of N-Ac indoles in hydroarylation reactions. R. K. Nandi, A. Perez-Luna, D. Gori, R. Beaud, R. Guillot, C. Kouklovsky, V. Gandon, G. Vincent, Adv. Synth. Catal., 2018, 360, 161–172

Light-Induced Activation of the Du Bois [RhII2(Esp)2] Catalyst for Nitrogen Atom Transfer Reactions. R. Farran, C. Ducloiset, J. Buendia, N. T. Vo, R. Guillot, Z. Halime, P. Dauban, W. Leibl, M. Sircoglou, A. Aukauloo, ChemPhotoChem, 2017, 1, 562-567

Acid-catalyzed reaction of 2-hydroxycyclobutanone with benzylic alcohols. A. Martis, A. Luridiana, A. Frongia, M. Arca, G. Sarais, D. J. Aitken, R. Guillot, F. Secci, Org. Biomol. Chem., 2017, 15, 10053-10063

Synthesis of 2,2-bis(pyridin-2-yl amino)cyclobutanols and their conversion into 5-(pyridin-2-ylamino)dihydrofuran-2(3H)-ones. L. Ghisu, N. Melis, F. Secci, P. Caboni, M. Arca, R. Guillot, T. Boddaert, D. J. Aitken, A. Frongia, Org. Biomol. Chem., 2017, 15, 9779-9784

Radical-Mediated Dearomatization of Indoles with Sulfinate Reagents for the Synthesis of Fluorinated Spirocyclic Indolines. D. Ryzhakov, M. Jarret, R. Guillot, C. Kouklovsky, G. Vincent, Org. Lett, 2017, 19, 6336-6339

The disentangling of hysteretic spin transition, polymorphism and metastability in bistable thin films formed by sublimation of bis(scorpionate) Fe(ii) molecules. O. Iasco, M.-L. Boillot, A. Bellec, R. Guillot, E. Riviere, S. Mazerat, S. Nowak, D. Morineau, A. Brosseau, F. Miserque, V. Repain, T. Mallah, J. Mater. Chem. C, 2017, 5, 11067-11075

Expedient Approach to α,β-Unsaturated δ-Lactones via a Catalytic Asymmetric [2+2] Cycloaddition. C. Kouklovsky, A. Rousseau, M. Buchotte, R. Guillot, G. Vincent, Eur. J. Org. Chem., 2017, 6804-6810

Stereoselective and regioselective pinacol-type rearrangement of a fused bicyclic oxetanol scaffold. N. Melis, A. Luridiana, R. Guillot, F. Secci, A. Frongia, T. Boddaert, D. J. Aitken, European Journal of Organic Chemistry, 2017, 2017, Issue 39, 5896–5902

Revealing the Activity of pi-Acid Catalysts Using a 7-Alkynyl Cycloheptatriene. V. Gandon, M. Vayer, R. Guillot, C. Bour, Chemistry – A European Journal, 2017, Volume 23, Issue 56, 13901–13905

Design of a Binuclear Ni(II) Complex with Large Ising-type Anisotropy and Weak Anti-Ferromagnetic Coupling. F. El-Khatib, B. Cahier, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, J.-J. Girerd, N. Guihéry, T. Mallah, Inorg. Chem., 2017, 56, 10655−10663

Imidazolidine Ring Cleavage upon Complexation with First Row Transition Metals. K. Cheaib, C. Herrero, R. Guillot, F. Banse, J.-P. Mahy, F. Avenier, Eur. J. Inorg. Chem., 2017, 3884-3891

Polymorphism, Mechanofluorochromism and Photophysical Characterization of a Carbonyl Substituted Difluoroboron-β-Diketone Derivative. M. Louis, A. Brosseau, R. Guillot, F. Ito, C. Allain, R. Métivier, J. Phys. Chem. C, 2017, 121 (29), 15897–15907

Rhenium Complexes Based on 2-Pyridyl-1,2,3-triazole Ligands: A New Class of CO2 Reduction Catalysts. H. Y. V. Ching, X. Wang, M. He, N. Perujo Holland, R. Guillot, C. Slim, S. Griveau, H. C. Bertrand, C. Policar, F. Bedioui, M. Fontecave, Inorg. Chem., 2017, 56, 2966-2976

Frozen Chirality of Tertiary Aromatic Amides :Access to Enantioenriched Tertiary alpha-Amino Acid or Amino Alcohol without Chiral Reagent. T. T. Mai, B. Viswambharan, D. Gori, R. Guillot, J.-V. Naubron, C. Kouklovsky, V. Alezra, Chem. Eur. J., 2017, 23, 5787-5798

Revealing the Electrophilicity of N-Ac Indoles with FeCl3: a mechanistic study. R. Beaud, R. K. Nandi, A. Perez-Luna, R. Guillot, D. Gori, C. Kouklovsky, N. E. Ghermani, V. Gandon, G. Vincent, Chem. Commun., 2017, 53, 5834 - 5837

Synthesis and characterization of FeII complexes with a BPMEN type ligand bearing π-accepting nitro groups. A. Bohn, K. Sénéchal-David, J. Vanoutryve, R. Guillot, E. Rivière, F. Banse, European Journal of Inorganic Chemistry, 2017, 3057-3063

Access to silver-NHC complexes from soluble silver species in aqueous or ethanolic ammonia. C. Gibard, K. Fauché, R. Guillot, L. Jouffret, M. Traïkia, A. Gautier, F. Cisnetti, Journal of Organometallic Chemistry, 2017, 840, 70-74

Synthesis of ribavirin 2’-Me-C-nucleoside analogues. F. Cosson, A. Faroux, J.-P. Baltaze, J. Farjon, R. Guillot, J. Uziel, N. Lubin-Germain, Beilstein Journal of Organic Chemistry, 2017, 13, 755-761

Conformational effects through hydrogen bonding in a constrained γ-peptide template: from intra-residue 7-membered rings to a gel-forming sheet structure. H. Awada, C. M. Grison, F. Charnay-Pouget, J.-P. Baltaze, F. Brisset, R. Guillot, S. Robin, A. Hachem, N. Jaber, D. Naoufal, O. Yazbeck, D. J. Aitken, J. Org. Chem., 2017, 82, 4819–4828

Design and Magnetic Properties of a Mononuclear Co(II) Single Molecule Magnet and Its Antiferromagnetically Coupled Binuclear Derivative. F. El-Khatib, B. Cahier, F. Shao, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, J.-J. Girerd, N. Guihéry, T. Mallah, Inorganic Chemistry, 2017, 56 (8), 4602–4609

Light-Controlled Release and Uptake of Zinc Ions in Solution by a Photochromic Terthiazole-Based Ligand. J. Guérin, A. Léaustic, J. Berthet, R. Métivier, R. Guillot, S. Delbaere, K. Nakatani, P. Yu, Chemistry – An Asian Journal, 2017, 12(8), 853–859

Evaluation of an NIS-Mediated Oxidative Cyclisation of Phenol-Containing N-Acyltryptamine Precursors towards Phalarine: Synthesis of 4′,5′-Dihydrospiro[indole-3,6′-[1,3]oxazine]s. T. Tomakinian, H. Abou Hamdan, N. Denizot, R. Guillot, J.-P. Baltaze, C. Kouklovsky, G. Vincent, Eur. J. Org. Chem., 2017, 19, 2757–2763

Unified biomimetic assembly of voacalgine A and bipleiophylline via divergent oxidative couplings. D. Lachkar, N. Denizot, G. Bernadat, K. Ahamada, M. A. Beniddir, V. Dumontet, J.-F. Gallard, R. Guillot, K. Leblanc, E. O. N'Nang, V. Turpin, C. Kouklovsky, E. Poupon, L. Evanno, G. Vincent, Nature Chemistry, 2017, 9, 793-798

Synthesis of C-Ribosyl-1,2,3-triazolyl Carboxamides. C. Solarte, M. Dos Santos, S. Gonzalez, L. S. M. Miranda, R. Guillot, A. Ferry, F. Gallier, J. Uziel, N. Lubin-Germain, Synthesis, 2017, 49(9), 1993-2002

Structural Dependence of the Ising-type Magnetic Anisotropy and of the Relaxation Time in Mononuclear Trigonal Bipyramidal Co(II) Single Molecule Magnets. F. Shao, B. Cahier, E. Rivière, R. Guillot, N. Guihéry, V. E. Campbell, T. Mallah, Inorg. Chem., 2017, 56, 1104-1111

Copper(II)-Controlled Molecular Glue for Mismatched DNA. N. Kotera, R. Guillot, M.-P. Teulade-Fichou, A. Granzhan, ChemBioChem, 2017, 18, Issue 7, 618–622

Studies on cyclization reactions of 3-amino-2,4-dihydroxybutanoic acid derivatives. M. Esgulian, V. Belot, R. Guillot, S. Deloisy, D. J. Aitken, Org. Biomol. Chem., 2017, 15, 1453-1462

Magnetic Anisotropy in Pentacoordinate Ni(II) and Co(II) Complexes: Unraveling Electronic and Geometrical Contributions. T. Mallah, B. Cahier, M. Perfetti, G. Zakhia, D. Naoufal, F. El-Khatib, R. Guillot, E. Rivière, R. Sessoli, A.-L. Barra, N. Guihéry, Chemistry – A European Journal, 2017, 23, 3648-3657

Synthesis of homoditopic ligands with an incrementable rodlike backbone. P. Demay-Drouhard, L.-M. Chamoreau, R. Guillot, C. Policar, H. C. Bertrand, European Journal of Organic Chemistry, 2017, 1, 131-137

Acid-catalysed intramolecular addition of [small beta]-ketoesters to 1,3-dienes. M. Vayer, W. Fang, R. Guillot, S. Bezzenine-Lafollee, C. Bour, V. Gandon, Org. Biomol. Chem., 2017, 15, 584-588

Synthesis, characterization and structural study of mercury(II) complexes with fluoroalkylthiocarbamates. I. Chniti, M. A. K. Sanhoury, H. Maouati, R. Guillot, D. Merlet, I. Chehidi, Journal of Molecular Structure, 2017, 1128, 64-69

Engineering the magnetic coupling and anisotropy at the molecule–magnetic surface interface in molecular spintronic devices. V. E. Campbell, M. Tonelli, I. Cimatti, J.-B. Moussy, L. Tortech, Y. J. Dappe, E. Rivière, R. Guillot, S. Delprat, R. Mattana, P. Seneor, P. Ohresser, F. Choueikani, E. Otero, F. Koprowiak, V. G. Chilkuri, N. Suaud, N. Guihéry, A. Galtayries, F. Miserque, M.-A. Arrio, P. Sainctavit, T. Mallah, Nature Communications, 2016, 7, 13646

Synthesis and Magnetic Characterization of Fe(III)-Based 9-Metallacrown-3 Complexes Which Exhibit Magnetorefrigerant Properties. C. Y. Chow, R. Guillot, E. Rivière, J. W. Kampf, T. Mallah, V. L. Pecoraro, Inorg. Chem., 2016, 55, 10238-10247

S-Trifluoromethyl Sulfoximine as a Directing Group in Ortho-Lithiation Reaction toward Structural Complexity. T.-N. Le, P. Diter, B. Pégot, C. Bournaud, M. Toffano, R. Guillot, G. Vo-Thanh, E. Magnier, Org. Lett., 2016, 18, 5102-5105

Organocatalyzed [4+2] Annulation of All-Carbon Tetrasubstituted Alkenes with Allenoates: Synthesis of Highly Functionalized 2H- and 4H-Pyran Derivatives. T.-T.-D. Ngo, K. Kishi, M. Sako, M. Shigenobu, C. Bournaud, M. Toffano, R. Guillot, J.-P. Baltaze, S. Takizawa, H. Sasai, G. Vo-Thanh, ChemistrySelect, 2016, 1, 5414-5420

Harnessing the Lewis Acidity of HFIP through its Cooperation with a Calcium(II) Salt: Application to the Aza-Piancatelli Reaction. D. Lebœuf, L. Marin, B. Michelet, A. Perez-Luna, R. Guillot, E. Schulz, V. Gandon, Chemistry – A European Journal, 2016, 22, 16165-16171

Catalytic applications of [IPr[middle dot]GaX2][SbF6] and related species. B. Michelet, S. Tang, G. Thiery, J. Monot, H. Li, R. Guillot, C. Bour, V. Gandon, Org. Chem. Front., 2016, 3, 1603-1613

Unraveling σ and π Effects on Magnetic Anisotropy in cis-NiA4B2 Complexes: Magnetization, HF-HFEPR Studies, First-Principles Calculations, and Orbital Modeling. G. Charron, E. Malkin, G. Rogez, L. J. Batchelor, S. Mazerat, R. Guillot, N. Guihéry, A.-L. Barra, T. Mallah, H. Bolvin, Chemistry – A European Journal, 2016, Volume 22, Issue 47, 16850–16862

Synthetic access to all four stereoisomers of oxetin. A. F. Kassir, S. S. Ragab, T. A. M. Nguyen, F. Charnay-Pouget, R. Guillot, M.-C. Scherrmann, T. Boddaert, D. J. Aitken, J. Org. Chem., 2016, 81, 9983-9991

Asymmetric Assisted Tandem Catalysis: Hydroamination followed by Asymmetric Friedel–Crafts Reaction from a Single Chiral N,N,N′,N′-Tetradentate Pyridylmethylamine-Based Ligand. A. Aillerie, V. Rodriguez-Ruiz, R. Carlino, F. Bourdreux, R. Guillot, S. Bezzenine-Lafollée, R. Gil, D. Prim, J. Hannedouche, ChemCatChem, 2016, 8, 2455–2460

Phosphine–Thiourea-Organocatalyzed Asymmetric C−N and C−S Bond Formation Reactions. T.-T.-D. Ngo, T.-H. Nguyen, C. Bournaud, R. Guillot, M. Toffano, G. Vo-Thanh, Asian Journal of Organic Chemistry, 2016, Volume 5, Issue 7, 895–899

Efficient synthesis of both diastereomers of β,γ-diamino acids from phenylalanine and tryptophan. N. Auberger, A. Stanovych, S. Thétiot-Laurent, R. Guillot, C. Kouklovsky, S. Cote Des Combes, C. Pacaud, I. Devillers, V. Alezra, Amino Acids, 2016, 48(9), 2237-2242

New insight into the structural, electrochemical and biological aspects of macroacyclic Cu(II) complexes derived from S-substituted dithiocarbazate schiff bases. M. L. Low, L. Maigre, M. I. M. Tahir, E. R.-T. Tiekink, P. Dorlet, R. Guillot, T. B. Ravoof, R. Rosli, J.-M. Pagès, C. Policar, N. Delsuc, K. A. Crouse, European Journal of Medicinal Chemistry, 2016, 120, 1-12

Synthesis of 3,3-Spiroindolines via FeCl3-Mediated Cyclization of Aryl- or Alkene-Containing 3-Substituted N-Ac Indoles. R. K. Nandi, R. Guillot, C. Kouklovsky, G. Vincent, Org. Lett., 2016, 18, 1716-1719

Synthesis of benzofuro[3,2-b]indoline amines via deamination-interrupted Fischer indolization and their unexpected reactivity towards nucleophiles. T. Tomakinian, R. Guillot, C. Kouklovsky, G. Vincent, Chem. Commun., 2016, 52, 5443-5446

Intermolecular dearomative C2-arylation of N-Ac indoles activated by FeCl3. R. K. Nandi, F. Ratsch, R. Beaud, R. Guillot, C. Kouklovsky, G. Vincent, Chem. Commun., 2016, 52, 5328-5331

Deracemizing organocatalyzed Michael addition reactions of 2-(arylthio)cyclobutanones with β-nitrostyrenes. A. Luridiana, A. Frongia, D. J. Aitken, R. Guillot, G. Sarais, F. Secci, Org. Biomol. Chem., 2016, 14, 3394-3403

A bis-MnII-DOTA complex for pulsed dipolar spectroscopy. P. Demay-Drouhard, H. Y.-V. Ching, D. Akhmetzyanov, R. Guillot, L. C. Tabares, H. C. Bertrand, C. Policar, ChemPhysChem, 2016, 17, 1-14

A New, Simple and Versatile Strategy for the Synthesis of Short Segments of Zigzag-Type Carbon Nanotubes. E. André, B. Boutonnet, P. Charles, C. Martini, J.-M. Aguiar-Hualde, S. Latil, V. Guérineau, K. Hammad, P. Ray, R. Guillot, V. Huc, Chemistry - A European Journal, 2016, 22(9), 3105-3114

Functionalized S-perfluorinated sulfoximines: preparation and evaluation in catalytic process. T.-N. Le, P. Diter, B. Pégot, C. Bournaud, M. Toffano, R. Guillot, G. Vo-Thanh, Y. Yagupolskii, E. Magnier, Journal of Florine Chemistry, 2015, 179, 179-187

Connecting Tyrosine and Tryptophan Units of Diazonamide A and Azonazine by a Diastereodivergent Arylative Dearomatization. N. Denizot, R. Guillot, C. Kouklovsky, G. Vincent, Chem. Eur. J., 2015, 21, 18953-18956

Monoanionic Dipyrrin–Pyridine Ligands: Synthesis, Structure and Photophysical Properties. C. Ducloiset, P. Jouin, E. Paredes, R. Guillot, M. Sircoglou, M. Orio, W. Leibl, A. Aukauloo, European Journal of Inorganic Chemistry, 2015, 2015, 5405-5410

Assessing the exchange coupling in binuclear lanthanide(iii) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy2 derivative. C. Y. Chow, H. Bolvin, V. E. Campbell, R. Guillot, J. W. Kampf, W. Wernsdorfer, F. Gendron, J. Autschbach, V. L. Pecoraro, T. Mallah, Chem. Sci., 2015, 6, 4148-4159

Gallium(III)- and calcium(II)-catalyzed Meyer-Schuster rearrangements followed by intramolecular aldol condensation or endo-Michael addition. M. Presset, B. Michelet, R. Guillot, C. Bour, S. Bezzenine-Lafollee, V. Gandon, Chem. Commun., 2015, 51, 5318-5321

First Evidence for the Existence of Hexafluoroantimonic(V) Acid. C. Bour, R. Guillot, V. Gandon, CHEMISTRY-A EUROPEAN JOURNAL, 2015, Volume: 21 Issue: 16, 6066-6069

Dibromoindium(III) cations as a pi-Lewis acid: characterization of [IPr center dot InBr2][SbF6] and its catalytic activity towards alkynes and alkenes. B. Michelet, J.-R. Colard-Itte, G. Thiery, R. Guillot, C. Bour, V. Gandon, CHEMICAL COMMUNICATIONS, 2015, Volume: 51 Issue: 34, 7401-7404

Tuning the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes. F. Shao, B. Cahier, N. Guihéry, E. Rivière, R. Guillot, A.-L. Barra, Y. Lan, W. Wernsdorfer, V. E. Campbell, T. Mallah, Chem. Commun., 2015, 51, 16475-16478

Imidazolium Dicarboxylate Based Metal–Organic Frameworks Obtained by Solvo-Ionothermal Reaction. P. Farger, R. Guillot, F. Leroux, N. Parizel, P. Gilliot, G. Rogez, E. Delahaye, P. Rabu, European Journal of Inorganic Chemistry, 2015, 32, 5342–5350

Enantioselective Organocatalyzed Desymmetrization of 3-Substituted Cyclobutanones through Michael Addition to Nitroalkenes. F. Capitta, A. Frongia, J. Ollivier, D. J. Aitken, F. Secci, P. P. Piras, R. Guillot, Synlett, 2015, 26, 123-126

Fine Tuning of β-Peptide Foldamers: a Single Atom Replacement Holds Back the Switch from an 8-Helix to a 12-Helix. A. Altmayer-Henzien, V. Declerck, J. Farjon, D. Merlet, R. Guillot, D. J. Aitken, Angewandte Chemie International Edition, 2015, 54, 10807-10810

Catalytic Enantioselective Synthesis of α-(Benzylamino)cyclobutanones. N. Melis, L. Ghisu, R. Guillot, P. Caboni, F. Secci, D. J. Aitken, A. Frongia, European Journal of Organic Chemistry, 2015, 2015, 4358-4366

An Artificial Enzyme Made by Covalent Grafting of an FeII Complex into β-Lactoglobulin: Molecular Chemistry, Oxidation Catalysis, and Reaction-Intermediate Monitoring in a Protein. C. Buron, K. Sénéchal-David, R. Ricoux, J.-P. Le Caër, V. Guérineau, P. Méjanelle, R. Guillot, C. Herrero, J.-P. Mahy, F. Banse, Chem. Eur. J., 2015, 21, 12188-12193

Aicd-base behavior, electrochemical properties and DFT study of redox non-innocent Phenol-Imidazol ligands and their Cu complexes. A. Parween, T. K. Tarun Kanti Mandal, R. Guillot, S. Naskar, Polyhedron, 2015, 99, 36-46

Entasis Through Hook-and-Loop Fastening in a Glycoligand with Cumulative Weak Forces Stabilizing CuI. L. Garcia, F. Cisnetti, N. Gillet, R. Guillot, M. Aumont-Nicaise, J.-P. Piquemal, M. Desmadril, F. Lambert, C. Policar, J. Am. Chem. Soc., 2015, 137 (3), 1141–1146

Synthesis, characterization and biological activity of Cu(II), Zn(II) and Re(I) complexes derived from Sbenzyldithiocarbazate and 3-acetylcoumarin. M. L. Low, P. Georgiana, P. Dorlet, R. Guillot, R. Rozita, D. Nicolas, K. A. Crouse, C. Policar, Biometals, 2015, 28-3, 553-566

Conformational preferences in the β-peptide oligomers of cis-2-amino-1-fluorocyclobutane-1-carboxylic acid. A. Hassoun, C. M. Grison, R. Guillot, T. Boddaert, D. J. Aitken, New J. Chem., 2015, 39, 3270-3279

Synthesis and characterization of [Fe(BPMEN)ACC]SbF₆: a structural and functional mimic of ACC-oxidase. Y. Roux, W. Ghattas, F. Avenier, R. Guillot, A. J. Simaan, J.-P. Mahy, Dalton Trans., 2015, 44, 5966-5968

Catalytic oxidation of dibenzothiophene and thioanisole by a diiron(III) complex and hydrogen peroxide. A. Trehoux, Y. Roux, R. Guillot, J.-P. Mahy, F. Avenier, Journal of Molecular Catalysis A: Chemical, 2015, 396, 40-46

FeII(pap-5NO2)2 and FeII(qsal-5NO2)2 Schiff-Base Spin-Crossover Complexes: A Rare Example with Photomagnetism and Room-Temperature Bistability. O. Iasco, E. Rivière, R. Guillot, M. Buron-Le Cointe, J.-F. Meunier, A. Bousseksou, M.-L. Boillot, Inorg. Chem., 2015, 54, 1791-1799

Fe(Me2-bpy)2(NCSe)2 spin-crossover micro- and nanoparticles showing spin-state switching above 250 K. L. L. Nguyen, R. Guillot, J. Laisney, L. Rechignat, S. Bedoui, G. Molnar, E. Riviere, M.-L. Boillot, New J. Chem., 2015, 39, 1603-1610

Synthesis and Characterization of New Chiral Azolinium Salts, Precursors to N-Heterocyclic Carbenes, Derived from l-Proline. A. Thomasset, L. Bouchardy, C. Bournaud, R. Guillot, M. Toffano, G. Vo-Thanh, Synthesis, 2014, 46, 242-250

Intramolecular photoinduced electron transfer in cobalt(II) chlathrochelate-zinc porphyrin assemblies leading to long-lived Co(I) species. S. El Ghachtouli, R. Guillot, W. Leibl, A. Aukauloo, Journal of Porphyrins and Phthalocyanines, 2014, 18, 1125-1130

Synthesis of spirolactonic C-sialosides induced by samarium diiodide. J. Pezzotta, D. Urban, R. Guillot, G. Doisneau, J.-M. Beau, Synlett, 2014, 25, 375-380

Structural, Magnetic, and Vibrational Investigations of FeIII Spin-Crossover Compounds [Fe(4-MeO–SalEen)2]X with X = NO3– and PF6–. A. Tissot, P. Fertey, R. Guillot, V. Briois, M.-L. Boillot, European Journal of Inorganic Chemistry, 2014, 2014, 101-109

Structure, Stability, and Catalytic Activity of Fluorine-Bridged Complexes IPr·GaCl2(μ-F)EFn–1 (EFn– = SbF6–, PF6–, or BF4–). C. Bour, J. Monot, S. Tang, R. Guillot, J. Farjon, V. Gandon, Organometallics, 2014, 33, 594-599

Light-induced excited spin state trapping effect on [Fe(mepy)3tren](PF6)2 solvated crystals. A. Tissot, E. Riviere, R. Guillot, L. Toupet, E. Collet, M.-L. Boillot, Dalton Trans., 2014, 43, 1063-1071

Structural and Electronic Dependence of the Single-Molecule-Magnet Behavior of Dysprosium(III) Complexes. V. E. Campbell, H. Bolvin, E. Rivière, R. Guillot, W. Wernsdorfer, T. Mallah, Inorganic Chemistry, 2014, 53, 2598-2605

Substrate Control in Enantioselective and Diastereoselective Aldol Reaction by Memory of Chirality: A Rapid Access to Enantiopure β-Hydroxy Quaternary α-Amino Acids. B. Viswambharan, D. Gori, R. Guillot, C. Kouklovsky, V. Alezra, Org. Lett., 2014, 16, 788-791

A unique 1-amino-1-cyclopropane carboxylate cupric-cryptate hosting sodium. W. Ghattas, R. Ricoux, H. Korri-Youssoufi, R. Guillot, E. Riviere, J.-P. Mahy, Dalton Trans., 2014, 43, 7708-7711

Luminescence Modulations of Rhenium Tricarbonyl Complexes Induced by Structural Variations. H. C. Bertrand, S. Clède, R. Guillot, F. Lambert, C. Policar, Inorganic Chemistry, 2014, 53, 6204-6223

First Isolation of Enantiopure Perfluoroalkylated Sulfilimines and Sulfoximines. T.-N. Le, E. Kolodziej, P. Diter, B. Pégot, C. Bournaud, M. Toffano, R. Guillot, G. Vo-Thanh, E. Magnier, CHIMIA International Journal for Chemistry, 2014, 68, 410-413

Well-Defined Four-Coordinate Iron(II) Complexes For Intramolecular Hydroamination of Primary Aliphatic Alkenylamines. E. Bernoud, P. Oulié, R. Guillot, M. Mellah, J. Hannedouche, Angewandte Chemie International Edition, 2014, 53, 4930-4934

’Auto-click’ functionalization for diversified copper(i) and gold(i) NHCs. H. Ibrahim, C. Gibard, C. Hesling, R. Guillot, L. Morel, A. Gautier, F. Cisnetti, Dalton Trans., 2014, 43, 6981-6989

Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes. L. J. Batchelor, I. Cimatti, R. Guillot, F. Tuna, W. Wernsdorfer, L. Ungur, L. F. Chibotaru, V. E. Campbell, T. Mallah, Dalton Trans., 2014, 43, 12146-12149

Regioselective Hydroarylation Reactions of C3 Electrophilic N-Acetylindoles Activated by FeCl3: An Entry to 3-(Hetero)arylindolines. R. Beaud, R. Guillot, C. Kouklovsky, G. Vincent, Chem. Eur. J., 2014, 20, 7492-7500

[Cu(IPr)2([small mu ]-OH)][BF4]: synthesis and halide-free CuAAC catalysis. H. Ibrahim, R. Guillot, F. Cisnetti, A. Gautier, Chem. Commun., 2014, 50, 7154-7156

Ising-type magnetic anisotropy and single molecule magnet behaviour in mononuclear trigonal bipyramidal Co(ii) complexes. R. Ruamps, L. J. Batchelor, R. Guillot, G. Zakhia, A.-L. Barra, W. Wernsdorfer, N. Guihery, T. Mallah, Chem. Sci., 2014, 5, 3418-3424

Electrochemical Implication of a Hydrogen-Bonded Imidazole on a Redox-Active-Bound Phenolate Group. S. El Ghachtouli, B. Lassalle-Kaiser, R. Guillot, A. Aukauloo, European Journal of Inorganic Chemistry, 2014, 2014, 4750-4755

A Multifunctional Photoswitch: 6π Electrocyclization versus ESIPT and Metalation. J. Guérin, A. Léaustic, S. Delbaere, J. Berthet, R. Guillot, C. Ruckebusch, R. Métivier, K. Nakatani, M. Orio, M. Sliwa, P. Yu, Chemistry – A European Journal, 2014, 20, 12279-12288

Synthesis of new biologically active isothiazolo[4,5-b]carbazole-type tetracyclic derivatives via an indole-2,3-quinodimethane approach. R. F. Miambo, M. Laronze-Cochard, A.-M. Lawson, R. Guillot, B. Baldeyrou, A. Lansiaux, C. T. Supuran, J. Sapi, Tetrahedron, 2014, 70, 8286-8302

Direct Oxidative Coupling of N-Acetyl Indoles and Phenols for the Synthesis of Benzofuroindolines Related to Phalarine. T. Tomakinian, R. Guillot, C. Kouklovsky, G. Vincent, Angew. Chem. Int. Ed., 2014, 53, 11881-11885

Bioinspired Direct Access to Benzofuroindolines by Oxidative [3 + 2] Annulation of Phenols and Indoles. N. Denizot, A. Pouilhès, M. Cucca, R. Beaud, R. Guillot, C. Kouklovsky, G. Vincent, Org. Lett., 2014, 16, 5752-5755

β,γ-Diamino acid: an original building block for hybrid α/γ-peptide synthesis with extra hydrogen bond donating group. A. Stanovych, R. Guillot, C. Kouklovsky, E. Miclet, V. Alezra, Amino Acids, 2014, 46, 2753-2757

Conjugation of a New Series of Dithiocarbazate Schiff Base Copper(II) Complexes with Vectors Selected to Enhance Antibacterial Activity. M. L. Low, L. Maigre, P. Dorlet, R. Guillot, J.-M. Pagès, K. A. Crouse, C. Policar, N. Delsuc, Bioconjugate Chemistry, 2014, 25, 2269-2284

Immobilization of an Anthracene-Tagged Ruthenium Complex on a 2,4,7-Trinitrofluoren-9-one-Grafted Silica: Efficiency and Recyclability in Olefin Metathesis Reactions. H. Nasrallah, A. Pagnoux, D. Didier, C. Magnier, L. Toupet, R. Guillot, C. Crévisy, M. Mauduit, E. Schulz, European Journal of Organic Chemistry, 2014, 2014, 7781-7787

Catalytic Enantioselective Synthesis of α-Arylaminocyclobutanones. D. J. Aitken, P. Caboni, H. Eijsberg, A. Frongia, R. Guillot, J. Ollivier, P. P. Piras, F. Secci, Adv. Synth. Catal., 2014, 356, 941-945

Practical Syntheses of Both Enantiomers of the Conformationally Restricted GABA Analogue cis-(2-Aminocyclobutyl)acetic Acid. H. Awada, S. Robin, R. Guillot, O. Yazbeck, D. Naoufal, N. Jaber, A. Hachem, D. J. Aitken, European Journal of Organic Chemistry, 2014, 2014, 7148-7155