Institut de Chimie Moléculaire et des Matériaux d'Orsay

Eric Riviere

Ingénieur de Recherche
Bât. 420LCI – ICMMO
Université Paris-Sud
15, rue Georges Clémenceau
91405 Orsay Cedex

+33 1 69 15 78 21



Planning SQUID


Publications récentes

Transforming a Diamagnetic Ordered Mesoporous Silica Monolith into a Room Temperature Permanent Magnet through Multiscale Control of the Magnetic Properties. V. Trannoy, L. Altenschmidt, G. Fornasieri, A. Bordage, E. Rivière, P. Beaunier, A. Bleuzen, ChemNanoMat, 2018, 4, 1254-1261

Magneto-Structural and Computational Study of a Tetranuclear Copper Complex Displaying Carbonyl–π Interactions. A. Kochem, B. Faure, S. Bertaina, E. Rivière, M. Giorgi, M. Réglier, M. Orio, A. J. Simaan, European Journal of Inorganic Chemistry, 2018, 0, 10.1002/ejic.201801032

Bicapped Keggin polyoxomolybdates: discrete species and experimental and theoretical investigations on the electronic delocalization in a chain compound. W. Salomon, E. Rivière, X. López, N. Suaud, P. Mialane, M. Haouas, A. Saad, J. Marrot, A. Dolbecq, Dalton Trans., 2018, 47, 10636-10645

Evidence of the Core–Shell Structure of (Photo)magnetic CoFe Prussian Blue Analogue Nanoparticles and Peculiar Behavior of the Surface Species. A. Bordage, R. Moulin, E. Fonda, G. Fornasieri, E. Rivière, A. Bleuzen, J. Am. Chem. Soc., 2018, 140, 10332-10343

Pressure-induced switching properties of the iron(III) spin transition complex [FeIII(3-OMeSalEen)2]PF6. J. Laisney, H. J. Shepherd, L. Rechignat, G. Molnar, E. Rivière, M.-L. Boillot, Physical Chemistry Chemical Physics, 2018, 15951-15959

Substituted versus Naked Thiourea Ligand Containing Pseudotetrahedral Cobalt(II) Complexes: A Comparative Study on Its Magnetization Relaxation Dynamics Phenomenon. S. Vaidya, P. Shukla, S. Tripathi, E. Rivière, T. Mallah, G. Rajaraman, M. Shanmugam, Inorg. Chem., 2018, 57, 3371-3386

A Bis-Binuclear NiII Complex with Easy and Hard Axes of Magnetization: Complementary Experimental and Theoretical Insights. F. El-Khatib, B. Cahier, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, N. Guihéry, T. Mallah, European Journal of Inorganic Chemistry, 2018, 2018, 469-476

Tuning the MnII2/MnIII2 redox cycle of a phenoxo-bridged diMn catalase mimic with terminal carboxylate donors. V. Solís, C. Palopoli, V. Daier, E. Rivière, F. Collin, D. M. Moreno, C. Hureau, S. Signorella, Journal of Inorganic Biochemistry, 2018, 182, 29-36

Anticancer Activity of Polyoxometalate-Bisphosphonate Complexes: Synthesis, Characterization, In Vitro and In Vivo Results. A. Boulmier, X. Feng, O. Oms, P. Mialane, E. Rivière, C. J. Shin, J. Yao, T. Kubo, T. Furuta, E. Oldfield, A. Dolbecq, Inorg. Chem., 2017, 56, 7558-7565

Macroscopic Magnetic Anisotropy Induced by the Combined Control of Size, Shape and Organization of NiFe Prussian Blue Analog Nanoparticles in an Ordered Mesoporous Silica Monolith. R. Moulin, G. Fornasieri, M. Impéror‐clerc, E. Rivière, P. Beaunier, A. Bleuzen, ChemNanoMat, 2017, 3, 833-840

Ci -Symmetry, [2 x 2] grid, square copper complex with the N4,N5-bis(4-fluorophenyl)-1H-imidazole-4,5-dicarboxamide ligand: structure, catecholase activity, magnetic properties and DFT calculations. A. Parween, S. Naskar, A. J. Mota, A. Espinosa Ferao, S. K. Chattopadhyay, E. Riviere, W. Lewis, S. Naskar, New J. Chem., 2017, 41, 11750-11758

Cubane-like tetranuclear Cu(ii) complexes bearing a Cu4O4 core: crystal structure, magnetic properties, DFT calculations and phenoxazinone synthase like activity. S. Sagar, S. Sengupta, A. J. Mota, S. K. Chattopadhyay, A. Espinosa Ferao, E. Riviere, W. Lewis, S. Naskar, Dalton Trans., 2017, 46, 1249-1259

Characterization of a Dinuclear Copper(II) Complex and Its Fleeting Mixed-Valent Copper(II)/Copper(III) Counterpart. A. Kochem, F. Gennarini, M. Yemloul, M. Orio, N. Le poul, E. Rivière, M. Giorgi, B. Faure, Y. Le mest, M. Réglier, A. J. Simaan, ChemPlusChem, 2017, 82, 615-624

The disentangling of hysteretic spin transition, polymorphism and metastability in bistable thin films formed by sublimation of bis(scorpionate) Fe(ii) molecules. O. Iasco, M.-L. Boillot, A. Bellec, R. Guillot, E. Riviere, S. Mazerat, S. Nowak, D. Morineau, A. Brosseau, F. Miserque, V. Repain, T. Mallah, J. Mater. Chem. C, 2017, 5, 11067-11075

Design of a Binuclear Ni(II) Complex with Large Ising-type Anisotropy and Weak Anti-Ferromagnetic Coupling. F. El-Khatib, B. Cahier, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, J.-J. Girerd, N. Guihéry, T. Mallah, Inorg. Chem., 2017, 56, 10655−10663

Spatially controlled positioning of coordination polymer nanoparticles onto heterogeneous nanostructured surfaces. V. Trannoy, M. Faustini, D. Grosso, F. Brisset, P. Beaunier, E. Riviere, M. Putero, A. Bleuzen, Nanoscale, 2017, 9, 5234-5243

Comparison of structural dynamics and coherence of d-d and MLCT light-induced spin state trapping. S. Zerdane, L. Wilbraham, M. Cammarata, O. Iasco, E. Riviere, M.-L. Boillot, I. Ciofini, E. Collet, Chem. Sci., 2017, 8, 4978-4986

Individual-collective crossover driven by particle size in dense assemblies of superparamagnetic nanoparticles. K. Ridier, B. Gillon, G. Chaboussant, L. Catala, S. Mazérat, E. Rivière, T. Mallah, European Physical Journal B, 2017, 90, 77

Synthesis and characterization of FeII complexes with a BPMEN type ligand bearing π-accepting nitro groups. A. Bohn, K. Sénéchal-David, J. Vanoutryve, R. Guillot, E. Rivière, F. Banse, European Journal of Inorganic Chemistry, 2017, 3057-3063

Design and Magnetic Properties of a Mononuclear Co(II) Single Molecule Magnet and Its Antiferromagnetically Coupled Binuclear Derivative. F. El-Khatib, B. Cahier, F. Shao, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, J.-J. Girerd, N. Guihéry, T. Mallah, Inorganic Chemistry, 2017, 56 (8), 4602–4609

Ordered Mesoporous Silica Monoliths as a Versatile Platform for the Study of Magnetic and Photomagnetic Prussian Blue Analogue Nanoparticles. R. Moulin, E. Delahaye, A. Bordage, E. Fonda, J.-P. Baltaze, P. Beaunier, E. Rivière, G. Fornasieri, A. Bleuzen, European Journal of Inorganic Chemistry, 2017, 2017, 1303-1313

Structural Dependence of the Ising-type Magnetic Anisotropy and of the Relaxation Time in Mononuclear Trigonal Bipyramidal Co(II) Single Molecule Magnets. F. Shao, B. Cahier, E. Rivière, R. Guillot, N. Guihéry, V. E. Campbell, T. Mallah, Inorg. Chem., 2017, 56, 1104-1111

Magnetic Anisotropy in Pentacoordinate Ni(II) and Co(II) Complexes: Unraveling Electronic and Geometrical Contributions. T. Mallah, B. Cahier, M. Perfetti, G. Zakhia, D. Naoufal, F. El-Khatib, R. Guillot, E. Rivière, R. Sessoli, A.-L. Barra, N. Guihéry, Chemistry – A European Journal, 2017, 23, 3648-3657

Synthesis, characterization and activity of imidazolate-bridged and Schiff-base dinuclear complexes as models of Cu,Zn-SOD. A comparative study. V. A. Daier, E. Rivière, S. Mallet-Ladeira, D. M. Moreno, C. Hureau, S. R. Signorella, Journal of Inorganic Biochemistry, 2016, 163, 162-175

Engineering the magnetic coupling and anisotropy at the molecule–magnetic surface interface in molecular spintronic devices. V. E. Campbell, M. Tonelli, I. Cimatti, J.-B. Moussy, L. Tortech, Y. J. Dappe, E. Rivière, R. Guillot, S. Delprat, R. Mattana, P. Seneor, P. Ohresser, F. Choueikani, E. Otero, F. Koprowiak, V. G. Chilkuri, N. Suaud, N. Guihéry, A. Galtayries, F. Miserque, M.-A. Arrio, P. Sainctavit, T. Mallah, Nature Communications, 2016, 7, 13646

Counterion-Induced Variations in the Dimensionality and Topology of Uranyl Pimelate Complexes. P. Thuéry, E. Rivière, J. Harrowfield, Crystal Growth & Design, 2016, 16, 2826-2835

Heteroanionic Materials Based on Copper Clusters, Bisphosphonates, and Polyoxometalates: Magnetic Properties and Comparative Electrocatalytic NOx Reduction Studies. O. Oms, S. Yang, W. Salomon, J. Marrot, A. Dolbecq, E. Rivière, A. Bonnefont, L. Ruhlmann, P. Mialane, Inorg. Chem., 2016, 55, 1551-1561

Synthesis and Magnetic Characterization of Fe(III)-Based 9-Metallacrown-3 Complexes Which Exhibit Magnetorefrigerant Properties. C. Y. Chow, R. Guillot, E. Rivière, J. W. Kampf, T. Mallah, V. L. Pecoraro, Inorg. Chem., 2016, 55, 10238-10247

Single-Molecule Magnet Behavior of Individual Polyoxometalate Molecules Incorporated within Biopolymer or Metal–Organic Framework Matrices. W. Salomon, Y. Lan, E. Rivière, S. Yang, C. Roch-Marchal, A. Dolbecq, C. Simonnet-Jégat, N. Steunou, N. Leclerc-Laronze, L. Ruhlmann, T. Mallah, W. Wernsdorfer, P. Mialane, Chemistry – A European Journal, 2016, 22, 6564-6574

Synthesis, X-ray structure and catecholase activity of an antiferromagnetically coupled trinuclear nickel(II) complex. A. Pal, S. C. Kumar, A. K. Ghosh, C.-H. Lin, E. Rivière, T. Mallah, R. Ghosh, Polyhedron, 2016, 110, 221-226

Polyoxomolybdate Bisphosphonate Heterometallic Complexes: Synthesis, Structure, and Activity on a Breast Cancer Cell Line. A. Saad, W. Zhu, G. Rousseau, P. Mialane, J. Marrot, M. Haouas, F. Taulelle, R. Dessapt, H. Serier-Brault, E. Rivière, T. Kubo, E. Oldfield, A. Dolbecq, Chemistry – A European Journal, 2015, 21, 10537-10547

Tuning the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes. F. Shao, B. Cahier, N. Guihéry, E. Rivière, R. Guillot, A.-L. Barra, Y. Lan, W. Wernsdorfer, V. E. Campbell, T. Mallah, Chem. Commun., 2015, 51, 16475-16478

Nanocrystals of Fe(phen)2(NCS)2 and the size-dependent spin-crossover characteristics. J. Laisney, A. Tissot, G. Molnar, L. Rechignat, E. Riviere, F. Brisset, A. Bousseksou, M.-L. Boillot, Dalton Trans., 2015, 44, 17302-17311

Magnetic Dextran Nanoparticles That Bear Hydrophilic Porphyrin Derivatives: Bimodal Agents for Potential Application in Photodynamic Therapy. J.-P. Mbakidi, F. Brégier, T.-S. Ouk, R. Granet, S. Alves, E. Rivière, S. Chevreux, G. Lemercier, V. Sol, ChemPlusChem, 2015, 80, 1416-1426

Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties. P. Thuéry, E. Rivière, J. Harrowfield, Inorg. Chem., 2015, 54, 2838-2850

FeII(pap-5NO2)2 and FeII(qsal-5NO2)2 Schiff-Base Spin-Crossover Complexes: A Rare Example with Photomagnetism and Room-Temperature Bistability. O. Iasco, E. Rivière, R. Guillot, M. Buron-Le Cointe, J.-F. Meunier, A. Bousseksou, M.-L. Boillot, Inorg. Chem., 2015, 54, 1791-1799

Fe(Me2-bpy)2(NCSe)2 spin-crossover micro- and nanoparticles showing spin-state switching above 250 K. L. L. Nguyen, R. Guillot, J. Laisney, L. Rechignat, S. Bedoui, G. Molnar, E. Riviere, M.-L. Boillot, New J. Chem., 2015, 39, 1603-1610

Hexanuclear, Heterometallic, Ni3Ln3 Complexes Possessing O-Capped Homo- and Heterometallic Structural Subunits: SMM Behavior of the Dysprosium Analogue. J. Goura, R. Guillaume, E. Rivière, V. Chandrasekhar, Inorg. Chem., 2014, 53, 7815-7823

Structural, magnetic and theoretical calculations of a ferromagnetically coupled tetranuclear copper(ii) square complex. L. Salmon, P. Thuery, E. Riviere, J.-P. Costes, A. J. Mota, M. Ephritikhine, New Journal of Chemistry, 2014, 38, 1306-1314

Photostrictive/Piezomagnetic Core–Shell Particles Based on Prussian Blue Analogues: Evidence for Confinement Effects? M. Presle, I. Maurin, F. Maroun, R. Cortès, L. Lu, R. Sayed Hassan, E. Larquet, J.-M. Guigner, E. Rivière, J. P. Wright, J.-P. Boilot, T. Gacoin, The Journal of Physical Chemistry C, 2014, 118, 13186-13195

Magnetization Reversal in CsNiIICrIII(CN)6 Coordination Nanoparticles: Unravelling Surface Anisotropy and Dipolar Interaction Effects. Y. Prado, S. Mazerat, E. Rivière, G. Rogez, A. Gloter, O. Stéphan, L. Catala, T. Mallah, Advanced Functional Materials, 2014, 24, 5402-5411

MnII-containing coordination nanoparticles as highly efficient T1 contrast agents for magnetic resonance imaging. G. Paul, Y. Prado, N. Dia, E. Riviere, S. Laurent, M. Roch, L. V. Elst, R. N. Muller, L. Sancey, P. Perriat, O. Tillement, T. Mallah, L. Catala, Chemical Communications, 2014, 50, 6740-6743

Trinuclear Manganese Complexes of Unsymmetrical Polypodal Diamino N3O3 Ligands with an Unusual [Mn3(μ-OR)4]5+ Triangular Core: Synthesis, Characterization, and Catalase Activity. G. N. Ledesma, E. Anxolabéhère-Mallart, E. Rivière, S. Mallet-Ladeira, C. Hureau, S. R. Signorella, Inorganic Chemistry, 2014, 53, 2545-2553

Solid-State Magnetic Switching Triggered by Proton-Coupled Electron-Transfer Assisted by Long-Distance Proton-Alkali Cation Transport. P. Higel, F. Villain, M. Verdaguer, E. Rivière, A. Bleuzen, Journal of the American Chemical Society, 2014, 136, 6231-6234

Neutral ferric complexes of salicylaldehyde thiosemicarbazone ligands: An exceptional family of complexes exhibiting discontinuous spin transition behavior. S. Floquet, E. Rivière, K. Boukheddaden, D. Morineau, M.-L. Boillot, Polyhedron, 2014, 80, 60-68

Assembly of heterobimetallic NiII-LnIII (LnIII = DyIII, TbIII, GdIII, HoIII, ErIII, YIII) complexes using a ferrocene ligand: slow relaxation of the magnetization in DyIII, TbIII and HoIII analogues. A. Chakraborty, P. Bag, E. Riviere, T. Mallah, V. Chandrasekhar, Dalton Transactions, 2014, 43, 8921-8932

Light-induced excited spin state trapping effect on [Fe(mepy)3tren](PF6)2 solvated crystals. A. Tissot, E. Riviere, R. Guillot, L. Toupet, E. Collet, M.-L. Boillot, Dalton Trans., 2014, 43, 1063-1071

Structural and Electronic Dependence of the Single-Molecule-Magnet Behavior of Dysprosium(III) Complexes. V. E. Campbell, H. Bolvin, E. Rivière, R. Guillot, W. Wernsdorfer, T. Mallah, Inorganic Chemistry, 2014, 53, 2598-2605

A unique 1-amino-1-cyclopropane carboxylate cupric-cryptate hosting sodium. W. Ghattas, R. Ricoux, H. Korri-Youssoufi, R. Guillot, E. Riviere, J.-P. Mahy, Dalton Trans., 2014, 43, 7708-7711