Institut de Chimie Moléculaire et des Matériaux d'Orsay

Chimie Inorganique

Nanosystèmes magnétiques

Talal Mallah (Prof), Laure Catala (Prof), Jean-Jacques Girerd (Prof. émerite), François Lambert (MCF), Sandra Mazerat (ADT, 50%), Eric Rivière (IR, 30%)

Postdoctorant : Sri Parshamoni

Doctorants : Mai Linh Trinh, Yiting Wang, Luqiong Zhang


Nous sommes intéressés par les aspects suivants de la chimie de coordination:

  1. Nanoparticules de coordination pour des applications biomédicales (L. Catala)
  2. Nanoparticules de coordination pour le stockage de l'information (L. Catala, S. Mazerat, T. Mallah)
  3. Molécules-aimants comme modèles de qbits multiples (T. Mallah, F. Lambert, J.-J. Girerd, E. Rivière)
  4. Films minces de molécules-aimants (T. Mallah, S. Mazerat)




En cours

Mai Linh Trinh — Nanocapteurs coeur-coquilles photomagnétiques commutables

Directrice de thèse : Laure Catala ; Co-directeur : Talal Mallah (Démarrée en janvier 2016)

Luqiong Zhang — Anisotropie magnétique de nanoparticules de coordination fonctionnelles : Etude expérimentale et théorique

Directeur de thèse : Talal Mallah ; Co-directeur : Philippe Sainctavit (IMPMC) (Démarrée en septembre 2015)

Yiting Wang  — Elaboration de dispositifs de spintronique basés sur des nano-aimants moléculaires

Directeur de thèse : Talal Mallah (Démarrée en novembre 2015)


Lucile Fetiveau — Nanoparticules de réseau de coordination à visée théranostique (2018)

Directrice de thèse : Laure Catala

Benjamin Cahier — Etude théorique de l'anisotropie magnétique dans des complexes de métaux de transition: Application à des complexes mono- et binucléraires de Ni(II) et Co(II) (2018)

Directeur de thèse : Talal Mallah ; Co-directrice de thèse : Nathalie Guihéry (LCPQ, Toulouse)

Fatima El-Khatib — Synthèse, caractérisation et études magnétiques de complexes de Co(II) et Ni(II) avec des ligands de type cryptands (2017)

Directeur de thèse : Talal Mallah ; Directrice de thèse : Zeinab Saad (Univ. Libanaise, Beyrouth) ; Co-directrice de thèse : Hala Hafez (Univ. Libanaise, Beyrouth)

Feng Shao — Ingénierie de l'anisotropie magnétique dans les complexes mononucléaires de cobalt(II) et les métallacrowns  à base de lanthanides (2017)

Directeur de thèse : Talal Mallah ; Co-encadrante: Victoria Campbell

Gabriella Paul — Nanoparticules de réseaux de coordination pour l'imagerie médicale (2015)

Directrice de thèse : Laure Catala

Georges Zakhia — Synthèse, caractérisation et propriétés magnétiques de nano-aimants moléculaires (2015)

Directeur de thèse : Talal Mallah ; Co-directeur de thèse : Daoud Naoufal (Univ. Libanaise, Beyrouth)

Nada Dia — Nanoparticules photomagnétiques et agents de contraste à base de réseaux de coordination (2013)

Directeur de thèse : Talal Mallah ; Co-directrice de thèse : Zeinad Saab (Univ. Libanaise, Beyrouth) ; Co-encadrante: Laure Catala

Yousuf RazaSpin crossover nanoparticles of Fe(pyrazyne)[Pt(CN)4]: Role of the environment on thermal stability (2013)

Directeur de thèse : Talal Mallah ; Co-encadrante: Laure Catala

Dernières publications (2016 - Auj.)

Tuning bimetallic catalysts for a selective growth of SWCNTs. S. Forel, A. Castan, H. Amara, I. Florea, F. Fossard, L. Catala, C. Bichara, T. Mallah, V. Huc, A. Loiseau, C.-S. Cojocaru, Nanoscale, 2019, 11, 4091-4100

Electronic and spin delocalization in a switchable trinuclear triphenylene trisemiquinone bridged Ni3 complex. Y. Wang, F. Lambert, E. Rivière, R. Guillot, C. Herrero, A. Tissot, Z. Halime, T. Mallah, Chem. Commun., 2019, 55, 12336-12339

Influence of a Counteranion on the Zero-Field Splitting of Tetrahedral Cobalt(II) Thiourea Complexes. S. Tripathi, S. Vaidya, K. U. Ansari, N. Ahmed, E. Rivière, L. Spillecke, C. Koo, R. Klingeler, T. Mallah, G. Rajaraman, M. Shanmugam, Inorg. Chem., 2019, 58, 9085-9100

Importance of Epitaxial Strain at a Spin-Crossover Molecule–Metal Interface. C. Fourmental, S. Mondal, R. Banerjee, A. Bellec, Y. Garreau, A. Coati, C. Chacon, Y. Girard, J. Lagoute, S. Rousset, M.-L. Boillot, T. Mallah, C. Enachescu, C. Barreteau, Y. J. Dappe, A. Smogunov, S. Narasimhan, V. Repain, J. Phys. Chem. Lett., 2019, 4103-4109

Surfaces, thin films and patterning of spin crossover compounds. T. Mallah, M. Cavallini, Comptes Rendus Chimie, 2018, 21, 1270-1286

Spin-crossover nanoparticles and nanocomposite materials. L. Salmon, L. Catala, Comptes Rendus Chimie, 2018, 10.1016/j.crci.2018.07.009

Substituted versus Naked Thiourea Ligand Containing Pseudotetrahedral Cobalt(II) Complexes: A Comparative Study on Its Magnetization Relaxation Dynamics Phenomenon. S. Vaidya, P. Shukla, S. Tripathi, E. Rivière, T. Mallah, G. Rajaraman, M. Shanmugam, Inorg. Chem., 2018, 57, 3371-3386

A Bis-Binuclear NiII Complex with Easy and Hard Axes of Magnetization: Complementary Experimental and Theoretical Insights. F. El-Khatib, B. Cahier, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, N. Guihéry, T. Mallah, European Journal of Inorganic Chemistry, 2018, 2018, 469-476

Probing Transient Photoinduced Charge Transfer in Prussian Blue Analogues with Time-Resolved XANES and Optical Spectroscopy. S. Zerdane, M. Cammarata, L. Balducci, R. Bertoni, L. Catala, S. Mazerat, T. Mallah, M. N. Pedersen, M. Wulff, K. Nakagawa, H. Tokoro, S.-I. Ohkoshi, E. Collet, European Journal of Inorganic Chemistry, 2018, 2018, 272-277

Temperature-, Light-, and Soft X-ray-Induced Spin Crossover in a Single Layer of FeII-Pyrazolylborate Molecules in Direct Contact with Gold. K. Bairagi, A. Bellec, C. Fourmental, O. Iasco, J. Lagoute, C. Chacon, Y. Girard, S. Rousset, F. Choueikani, E. Otero, P. Ohresser, P. Sainctavit, M.-L. Boillot, T. Mallah, V. Repain, J. Phys. Chem. C, 2018, 122, 727-731

Hysteresis in a bimetallic holmium complex: A synergy between electronic and nuclear magnetic interactions. M. Viciano-Chumillas, F. Koprowiak, I. Mutikainen, W. Wernsdorfer, T. Mallah, H. Bolvin, Physical Review B, 2017, 96, 214427

New method for the growth of single-walled carbon nanotubes from bimetallic nanoalloy catalysts based on Prussian blue analog precursors. A. Castan, S. Forel, L. Catala, I. Florea, F. Fossard, F. Bouanis, A. Andrieux-Ledier, S. Mazerat, T. Mallah, V. Huc, A. Loiseau, C. Sorin-Cojocaru, Carbon, 2017, 123, 583-592

The disentangling of hysteretic spin transition, polymorphism and metastability in bistable thin films formed by sublimation of bis(scorpionate) Fe(ii) molecules. O. Iasco, M.-L. Boillot, A. Bellec, R. Guillot, E. Riviere, S. Mazerat, S. Nowak, D. Morineau, A. Brosseau, F. Miserque, V. Repain, T. Mallah, J. Mater. Chem. C, 2017, 5, 11067-11075

A bird's eye view on the flat and conic band world of the honeycomb and Kagome lattices: towards an understanding of 2D metal-organic frameworks electronic structure. C. Barreteau, F. Ducastelle, T. Mallah, Journal of Physics: Condensed Matter, 2017, 29, 465302

Nanoparticles of Prussian blue analogs and related coordination polymers: From information storage to biomedical applications. L. Catala, T. Mallah, Coordination Chemistry Reviews, 2017, 346, 32-61

Design of a Binuclear Ni(II) Complex with Large Ising-type Anisotropy and Weak Anti-Ferromagnetic Coupling. F. El-Khatib, B. Cahier, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, J.-J. Girerd, N. Guihéry, T. Mallah, Inorg. Chem., 2017, 56, 10655−10663

Individual-collective crossover driven by particle size in dense assemblies of superparamagnetic nanoparticles. K. Ridier, B. Gillon, G. Chaboussant, L. Catala, S. Mazérat, E. Rivière, T. Mallah, European Physical Journal B, 2017, 90, 77

Design and Magnetic Properties of a Mononuclear Co(II) Single Molecule Magnet and Its Antiferromagnetically Coupled Binuclear Derivative. F. El-Khatib, B. Cahier, F. Shao, M. López-Jordà, R. Guillot, E. Rivière, H. Hafez, Z. Saad, J.-J. Girerd, N. Guihéry, T. Mallah, Inorganic Chemistry, 2017, 56 (8), 4602–4609

Structural Dependence of the Ising-type Magnetic Anisotropy and of the Relaxation Time in Mononuclear Trigonal Bipyramidal Co(II) Single Molecule Magnets. F. Shao, B. Cahier, E. Rivière, R. Guillot, N. Guihéry, V. E. Campbell, T. Mallah, Inorg. Chem., 2017, 56, 1104-1111

Magnetic Anisotropy in Pentacoordinate Ni(II) and Co(II) Complexes: Unraveling Electronic and Geometrical Contributions. T. Mallah, B. Cahier, M. Perfetti, G. Zakhia, D. Naoufal, F. El-Khatib, R. Guillot, E. Rivière, R. Sessoli, A.-L. Barra, N. Guihéry, Chemistry – A European Journal, 2017, 23, 3648-3657

Engineering the magnetic coupling and anisotropy at the molecule–magnetic surface interface in molecular spintronic devices. V. E. Campbell, M. Tonelli, I. Cimatti, J.-B. Moussy, L. Tortech, Y. J. Dappe, E. Rivière, R. Guillot, S. Delprat, R. Mattana, P. Seneor, P. Ohresser, F. Choueikani, E. Otero, F. Koprowiak, V. G. Chilkuri, N. Suaud, N. Guihéry, A. Galtayries, F. Miserque, M.-A. Arrio, P. Sainctavit, T. Mallah, Nature Communications, 2016, 7, 13646

Synthesis and Magnetic Characterization of Fe(III)-Based 9-Metallacrown-3 Complexes Which Exhibit Magnetorefrigerant Properties. C. Y. Chow, R. Guillot, E. Rivière, J. W. Kampf, T. Mallah, V. L. Pecoraro, Inorg. Chem., 2016, 55, 10238-10247

Unraveling σ and π Effects on Magnetic Anisotropy in cis-NiA4B2 Complexes: Magnetization, HF-HFEPR Studies, First-Principles Calculations, and Orbital Modeling. G. Charron, E. Malkin, G. Rogez, L. J. Batchelor, S. Mazerat, R. Guillot, N. Guihéry, A.-L. Barra, T. Mallah, H. Bolvin, Chemistry – A European Journal, 2016, Volume 22, Issue 47, 16850–16862

Tools for Predicting the Nature and Magnitude of Magnetic Anisotropy in Transition Metal Complexes: Application to Co(II) Complexes. B. Cahier, R. Maurice, H. Bolvin, T. Mallah, N. Guihéry, Magnetochemistry, 2016, 2, 31

Molecular-scale dynamics of light-induced spin cross-over in a two-dimensional layer. K. Bairagi, O. Iasco, A. Bellec, A. Kartsev, D. Li, J. Lagoute, C. Chacon, Y. Girard, S. Rousset, F. Miserque, Y. J. Dappe, A. Smogunov, C. Barreteau, M.-L. Boillot, T. Mallah, V. Repain, Nat Commun, 2016, 7, 12212

Single-Molecule Magnet Behavior of Individual Polyoxometalate Molecules Incorporated within Biopolymer or Metal–Organic Framework Matrices. W. Salomon, Y. Lan, E. Rivière, S. Yang, C. Roch-Marchal, A. Dolbecq, C. Simonnet-Jégat, N. Steunou, N. Leclerc-Laronze, L. Ruhlmann, T. Mallah, W. Wernsdorfer, P. Mialane, Chemistry – A European Journal, 2016, 22, 6564-6574

Synthesis, X-ray structure and catecholase activity of an antiferromagnetically coupled trinuclear nickel(II) complex. A. Pal, S. C. Kumar, A. K. Ghosh, C.-H. Lin, E. Rivière, T. Mallah, R. Ghosh, Polyhedron, 2016, 110, 221-226