Chimie Inorganique
Mixed hybridization systems : Towards the "after C60"
Vincent Huc (Research Dir.)
Postdoc : Dr. Julien Buendia, Dr. Timothée Naret, Dr. Alberto Diez De La Varga
PhD students : Thomas Blin, Abdoul-Nasser Moussa-Bamba
Associate researchers : Cyril Martini (NOVECAL), Ekaterina Shilova (AJELIS)
The research of the group is developped around 5 axes :
- Calixarene-based materials for decontamination and recovery of strategic metals
- Calixarenes-supported catalysts
- Giant calixarenes : a new family of macromolecular objects
- Towards the total synthesis of SWCN (Single-Walled Carbon Nanotubes)
- Surface chemistry for the in-growth control of the electronic properties of SWCNTs
PhD theses
Ongoing
Abdoul-Nasser Moussa-Bamba — Towards the total synthesis of carbon nanotubes
PhD advisor : Vincent Huc (Started in october 2020)
Thomas Blin — Nanoalloys for the in growth control of the structure of carbon nanotubes
PhD advisor : Vincent Huc ; Co-advisor : Annick Loiseau (ONERA, Palaiseau)(Started in november 2019)
Defended
Axel Labattut— Catalysts based on organometallic complexes on calixarenes (2021)
PhD advisor : Vincent Huc
Alice Castan — Growth and characterization of single-walled carbon nanotubes from chemically synthesized catalyst precursors (2018)
PhD advisors : Vincent Huc and Annick Loiseau (LEM, Palaiseau)
Marie Clément — Calixarenes for the radiolytic synthesis of metallic nanoparticles (2017)
PhD advisor : Isabelle Lampre (LCP, Orsay) ; Co-advisor : Cyril Martini
Baptiste Boutonnet — Towards the total synthesis of Zig-Zag single walled carbon nanotubes with well-defined diameters (2014)
PhD advisor : Vincent Huc
Last publications (2016 - Today)
Synthesis and characterization of polystyrene-b-poly(vinyldipicolinic acid) pH-responsive core-shell nanoparticles. A. W. Mouhamad, T. Elzein, N. Barroca-Aubry, E. Simoni, N. Berri, F. Brisset, V. Huc, P. Roger, European Polymer Journal, 2023, 201, 112541
η-Carbides (Co, Mo, or W) Nanoparticles from Octacyanometalates Precursors-Based Network. T. Blin, A. Girard, F. Fossard, N. Guillou, L. Catala, A. Loiseau, V. Huc, Small, 2023, n/a, 2301299
Structural Size Effect in Capped Metallic Nanoparticles. C. Moreira Da Silva, A. Girard, Y. Le Bouar, F. Fossard, D. Dragoe, F. Ducastelle, A. Loiseau, V. Huc, ACS Nano, 2023, 17, 5663-5672
A simple and efficient process for the synthesis of 2D carbon nitrides and related materials. C. Moreira Da Silva, M. Vallet, C. Semion, T. Blin, R. Saint-Martin, J. Leroy, D. Dragoé, F. Brisset, C. Gillet, R. Guillot, V. Huc, Scientific Reports, 2023, 13, 15423
Synthesis and structural properties of high-entropy nanoalloys made by physical and chemical routes. A. Barbero, C. Moreira da Silva, N. Ortiz Pena, N. Kefane, A. Jaafar, M. Thorey, H. Bouaia, J. Nelayah, G. Wang, H. Amara, C. Ricolleau, V. Huc, D. Alloyeau, Faraday Discuss., 2022
A Calix[8]arene-Based Catalyst for Suzuki–Miyaura Couplings with Reduced Pd_Leaching. E. Adhel, A. Labattut, T. Naret, D. Dragoe, V. Huc, Catalysts, 2022, 12
Colloidal Synthesis of Nanoparticles: from Bimetallic to High Entropy Alloys. C. Moreira Da Silva, H. Amara, F. Fossard, A. Girard, V. Huc, A. Loiseau, Nanoscale, 2022, 14, 9832-9841
Synthesis, Catalytic Activity and Comparative Leaching Studies of Calix[8]arene-Supported Pd-NHC Complexes for Suzuki-Miyaura Cross-Couplings. S. Abi Fayssal, T. Naret, J. Buendia, A. Labattut, V. Huc, C. Martini, E. Schulz, Advanced Synthesis & Catalysis, 2022, 364, 947-957
Benzyloxycalix[8]arene supported Pd–NHC cinnamyl complexes for Buchwald–Hartwig C–N cross-couplings. S. Abi Fayssal, T. Naret, V. Huc, J. Buendia, C. Martini, E. Schulz, Catal. Sci. Technol., 2021, 11, 5223-5231
A Self-Assembling NHC-Pd-Loaded Calixarene as a Potent Catalyst for the Suzuki-Miyaura Cross-Coupling Reaction in Water. A. Peramo, I. Abdellah, S. Pecnard, J. Mougin, C. Martini, P. Couvreur, V. Huc, D. Desmaële, Molecules, 2020, 25
Palladium PEPPSI-IPr Complex Supported on a Calix[8]arene: A New Catalyst for Efficient Suzuki–Miyaura Coupling of Aryl Chlorides. A. Labattut, I. Abdellah, J. Buendia, S. Abi Fayssal, E. Adhel, D. Dragoe, C. Martini, E. Schulz, V. Huc, Catalysts, 2020, 10, 1081
Nickel platinum (NixPt1−x) nanoalloy monodisperse particles without the core–shell structure by colloidal synthesis. C. Moreira Da Silva, A. Girard, M. Dufond, F. Fossard, A. Andrieux-Ledier, V. Huc, A. Loiseau, Nanoscale Adv., 2020, 2, 3882-3889
Gold(i)–silver(i)-calix[8]arene complexes, precursors of bimetallic alloyed Au–Ag nanoparticles. M. Clément, I. Abdellah, C. Martini, F. Fossard, D. Dragoe, H. Remita, V. Huc, I. Lampre, Nanoscale Adv., 2020, 2, 2768-2773
Calixarene-supported Pd–NHC complexes as efficient catalysts for scalable Suzuki–Miyaura cross–couplings. A. Labattut, S. Abi Fayssal, J. Buendia, I. Abdellah, V. Huc, C. Martini, E. Schulz, React. Chem. Eng., 2020, 5, 1509-1514
Synthesis and NMR study of trimethylphosphine gold(i)-appended calix[8]arenes as precursors of gold nanoparticles. M. Clément, I. Abdellah, P. Ray, C. Martini, Y. Coppel, H. Remita, I. Lampre, V. Huc, Inorg. Chem. Front., 2020, 7, 953-960
Ajelis et Novecal – Des molécules-cages aux fibres extractantes et à la catalyse. E. Schulz, E. Shilova, P. Viel, G. Gros, C. Martini, I. Abdellah, V. Huc, Actualité Chimique, 2019, mars-avril, 30 – 39
Plasmonic catalysis for the Suzuki–Miyaura cross-coupling reaction using palladium nanoflowers. I. Sarhid, I. Abdellah, C. Martini, V. Huc, D. Dragoe, P. Beaunier, I. Lampre, H. Remita, New J. Chem., 2019, 43, 4349-4355
Tuning bimetallic catalysts for a selective growth of SWCNTs. S. Forel, A. Castan, H. Amara, I. Florea, F. Fossard, L. Catala, C. Bichara, T. Mallah, V. Huc, A. Loiseau, C.-S. Cojocaru, Nanoscale, 2019, 11, 4091-4100
The synthesis and characterization of giant Calixarenes. V. Guérineau, M. Rollet, S. Viel, B. Lepoittevin, L. Costa, P. Saint-Aguet, R. Laurent, P. Roger, D. Gigmes, C. Martini, V. Huc, Nature Communications, 2019, 10, 113
Calix[8]arene as New Platform for Cobalt-Salen Complexes Immobilization and Use in Hydrolytic Kinetic Resolution of Epoxides. I. Abdellah, C. Martini, A. Dos santos, D. Dragoe, V. Guérineau, V. Huc, E. Schulz, ChemCatChem, 2018, 10, 4761-4767
Benzyloxycalix[8]arene: a new valuable support for NHC palladium complexes in C–C Suzuki–Miyaura couplings. I. Abdellah, P. Kasongo, A. Labattut, R. Guillot, E. Schulz, C. Martini, V. Huc, Dalton Trans., 2018, 47, 13843-13848
Stabilisation of small mono- and bimetallic gold–silver nanoparticles using calix[8]arene derivatives. P. Ray, M. Clément, C. Martini, I. Abdellah, P. Beaunier, J.-L. Rodriguez-Lopez, V. Huc, H. Remita, I. Lampre, New J. Chem., 2018, 42, 14128-14137
New method for the growth of single-walled carbon nanotubes from bimetallic nanoalloy catalysts based on Prussian blue analog precursors. A. Castan, S. Forel, L. Catala, I. Florea, F. Fossard, F. Bouanis, A. Andrieux-Ledier, S. Mazerat, T. Mallah, V. Huc, A. Loiseau, C. Sorin-Cojocaru, Carbon, 2017, 123, 583-592
A New, Simple and Versatile Strategy for the Synthesis of Short Segments of Zigzag-Type Carbon Nanotubes. E. André, B. Boutonnet, P. Charles, C. Martini, J.-M. Aguiar-Hualde, S. Latil, V. Guérineau, K. Hammad, P. Ray, R. Guillot, V. Huc, Chemistry - A European Journal, 2016, 22(9), 3105-3114
Patents
Novel complexes for the separation of metal cations in liquid medium. V. Huc, P. Viel, E. Shilova (2015) WO/2015/150588
Procédé de préparation à hauts rendements de p-(R)calix[9-20]arènes. C. Martini, V. Huc (2014) 14/51660 WO/2014/033406
Procédé de préparation à hauts rendements de p-(R)calixarènes géants. C. Martini, V. Huc (2014) WO/2014/033407
Procédé de préparation à hauts rendements de p-(R)calix[9-20]arènes. C. Martini, V. Huc (2014) 14/51660
Solid-liquid process for extraction of radionuclides from waste solutions. E. Shilova, P. Viel, V. Huc, V. Barré (2013) WO/2013/124831
Synthèse à hauts rendements de p-(benzyloxy)calix[6,7,8]arènes. C. Martini, V. Huc (2013) WO/2013/088056
Cryptands à base de calix[4]arènes associés à un macrocycle azoté et leur utilisation pour l’extraction sélective de métaux stratégiques (Déposé le 11/10/2017) Brevet français n° FR1759523
Catalyseurs supportés cycliques (Brevet déposé le 27.10.2016) Brevet français n° FR16/60471
Last update on Feb. 28th 2022