Institut de Chimie Moléculaire et des Matériaux d'Orsay

Laboratoire de Chimie Inorganique - LCI

Anne Bleuzen


Bat 420, RdC Aile B - Bureau 055A

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Research :

From Molecular Switches to nanoscale memories and switching Devices


Recent publications :

Mixed valency and magnetism in cyanometallates and Prussian blue analogues.
J. M. Herrera, A. Bachschmidt, F. Villain, A. Bleuzen, V. Marvaud, W. Wensdorfer and M. Verdaguer, Phyl. Trans. R. Soc., 366,127-138, 2008.

Metal dilution effects on the swicthing properties of CoFe Prussian blue analogues
J. D. Cafun, L. Londinière, E. Rivière and A. Bleuzen. Inorganica Chimica Acta, 361, 12-13, 3555-3563, 2008.

Thermally-activated charge transfer in a Prussian blue derivative probed by resonant inelastic x-ray scattering
I. Jarrige, Y. Q. Cai, H. Ishii, N. Hiraoka, A. Bleuzen, Applied Physics Letters, 93, 054101, 2008.

Controlled Synthesis of Photomagnetic Nanoparticles of Prussian Blue Analogue in a Silica Xerogel.
G. Fornasieri, A. Bleuzen, Angew. Chem. Int. Ed., 47,  7750-7752, 2008.

CoFe Prussian blue analogues under variable pressure : Evidence of departure from cubic symmetry. An X-ray diffraction and absorption study.
A. Bleuzen, J.-D. Cafun, A. Bachschmidt, M. Verdaguer, P. Münsch, F. Baudelet, J.-P. Itié, J. Phys. Chem. C, 112, 17709-17715, 2008.

Photomagnetism in Clusters and Extended Molecule-Based Magnets
A. Bleuzen, V. Marvaud, C. Mathonière, B. Sieklucka, M. Verdaguer, Inorg. Chem., 48, 3453-3466, 2009.

Optical and magnetic properties of the photo-induced state in the coordination network Na2Co4[Fe(CN)6]3,3*14H2O.
R. Le Bris, J.-D. Cafun, C. Mathonière, A. Bleuzen, J.-F. Létard, New J. Chem., 33, 1255 – 1261, 2009.

Evidence for complex multistability in photomagnetic cobalt hexacyanoferrates from combined magnetic and synchrotron x-ray diffraction measurements.
I. Maurin, D. Chernyshov, F. Varret, A. Bleuzen, H. Tokoro, K. Hashimoto, S.-I. Ohkoshi, Phys. Rev. B 79, 064420, 2009.

Tailor-made Nano-scale Patterns of Photo-Switchable Prussian blue Analogs..
S. Lepoutre, D. Grosso, C. Sanchez, G. Fornasieri, E. Rivière, A. Bleuzen, Adv. Mater., 22, 3992–3996, 2010.

Control of stoichiometry, size and morphology of inorganic polymers by template assisted coordination chemistry
P. Durand, G. Fornasieri, C. Baumier, P. Beaunier, D. Durand, E. Rivière, A. Bleuzen, J. Mater. Chem., 20, 9348-9354, 2010.

Photomagnetic CoFe Prussian blue Analogues :Role of the Cyanide ions as Active Electron Transfer Bridges Modulated by Cyanide-Alkali Metal ions Interactions.
J.-D. Cafun, G. Champion, M.-A. Arrio, C. Cartier dit Moulin, A. Bleuzen, J. Am. Chem. Soc., 132, 11552-11559, 2010.

Fully Controlled Precipitation of Photomagnetic CoFe Prussian Blue Analogue Nanoparticles within the Ordered Mesoporosity of Silica Monoliths.
G. Fornasieri, M. Aouadi, P. Durand, P. Beaunier, E. Rivière, A. Bleuzen, Chem. Commun., 46, 8061-8063, 2010

Chemical model of intermediate states implied in the switching properties of CoFe Prussian blue analogues: How a cell parameter lengthening can cause a crystal field parameter increase.
J.-D. Cafun, C. Cartier dit Moulin, G. Fornasieri, M.-A. Arrio, V. Briois, A. Bleuzen, New J. Chem., 35, 2074-2080, 2011.

Co2+ ions-containing ordered silica monoliths: Influence of the copolymer P123/Si and Co2+ ions/Si ratios on the organization of the monoliths.
E. Delahaye, M. Aouadi, D. Durand, P. Beaunier, G. Fornasieri, A. Bleuzen, Mater. Res. Soc. Symposium Proceedings Series, 1359, 2011. DOI:10.1557/opl.2011.88

Chemistry of cobalt(II) confined in the pores of ordered silica monoliths: from the elaboration of the monolith to the CoFe Prussian blue analogue nanocomposite.
M. Aouadi, G. Fornasieri, V. Briois, P. Durand, A. Bleuzen, Chem. Eur. J., 2012, in press.

Elaboration of Prussian blue analogue / silica nanocomposites: towards tailor-made nano-scale electronic devices.
G. Fornasieri, M. Aouadi, E. Delahaye, P. Beaunier, D. Durand, E. Rivière, P.-A. Albouy, F. Brisset, A. Bleuzen, Materials, 2012, in press.