Institut de Chimie Moléculaire et des Matériaux d'Orsay

Laboratoire de Chimie Bioorganique et Bioinorganique - LCBB

Frédéric Avenier

Frédéric Avenier


Maître de Conférences 

UMR 8182, ICMMO
Institut de Chimie Moléculaire et des Matériaux d’Orsay
Université Paris-Sud, Bât 420
91405 Orsay Cedex

Tel : 01 69 15 47 23
Fax : 0 1 69 15 72 81

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Domaines de recherche :
Thème 2

Enseignements :

Publications (2004-2017) :


Imidazolidine Ring Cleavage upon Complexation with First Row Transition Metals.
Khaled CHEAIB, Christian HERRERO, Régis GUILLOT, Fréderic BANSE, Jean-Pierre MAHY, and Frédéric AVENIER
Eur. J. Inorg. Chem. 2017, 3884-3891.

Redox Self-Adaptation of a Nitrene Transfer Catalyst to the Substrate Needs.
Eric Gouré, Dhurairajan Senthilnathan, Guillaume Coin, Florian Albrieux, Frédéric Avenier, Patrick Dubourdeaux, Colette Lebrun, Pascal Maldivi, Jean-Marc Latour
Angew. Chem. Int. Ed. 2017, 56, 4305-4309.


Elucidating the light-induced charge accumulation in an artificial analogue of methane monooxygenase enzymes using time-resolved x-ray absorption spectroscopy.
Dooshaye MOONSHIRAM, Antonio PICON, Alvaro VASQUEZ-MAYAGOITIA, Xiaoyi ZHANG, Ming-Feng TU, Pablo GARRIDO-BARROS, Jean-Pierre MAHY, Frédéric AVENIER and Ally AUKAULOO
Chem. Commun. 2017, 53, 2725-2728
.

Reduction of a Tris(picolyl)amine Copper(II) Complex by a Polymeric Flavo-Reductase Model in Water.
Khaleb CHEAIB, Yoann ROUX, Christian HERRERO, Alexandre TREHOUX, Frédéric AVENIER and Jean-Pierre MAHY
Dalton Trans. 2016, 45, 18098-18101
.

A growing family of O2 activating dinuclear iron enzymes with key catalytic diiron(III)-peroxo intermediates: biological systems and chemical models.
Alexandre TREHOUX, Jean-Pierre MAHY, Frédéric AVENIER
Coord. Chem. Rev. 2016, 322, 142-158
.

Bio-inspired electron-delivering system for reductive activation of dioxygen at metal centres towards artificial flavoenzymes.
Yoann ROUX, Rémy RICOUX, Frédéric AVENIER, Jean-Pierre MAHY
Nat. Commun. 2015, 6, 8509.

Synthesis and characterization of [Fe(BPMEN)-ACC]SbF6: a structural and functional mimic of ACC-oxidase.
Yoann ROUX, Wadih GHATTAS, Frédéric AVENIER, Régis GUILLOT, A. Jalila SIMAAN and Jean-Pierre MAHY
Dalton Trans. 2015, 44, 5966-5968.

Catalytic Oxidation of Dibenzothiophene and thioanisole by a Diiron(III) Complex and Hydrogen Peroxide.
Alexandre TREHOUX, Yoann ROUX, Régis GUILLOT, Jean-Pierre MAHY, Frédéric AVENIER
J. Mol. Catal. A : Chem. 2015, 396, 40-46.

Neocarzinostatin-based hybrid biocatalysts with a RNase like activity.
Agathe URVOAS, Wadih GHATTAS, Jean-Didier MARECHAL, Frédéric AVENIER, Felix BELLANDE, Wei MAO, Rémy RICOUX, Jean-Pierre MAHY
Bioorg. Med. Chem. 2014, 22, 5678-5686.

A Diiron(III,IV) Imido Species Very Active in Nitrene-Transfer Reactions.
Eric GOURE, Frédéric AVENIER, Patrick DUBOURDEAUX, Olivier SENEQUE, Florian ALBRIEUX, Colette LEBRUN, Martin CLEMANCEY, Pascale MALDIVI, Jean-Marc LATOUR
Angew. Chem. Int. Ed. 2014, 53, 1580-1584.

Photoassisted Generation of a Dinuclear Iron(III) Peroxo Species and Oxygen-Atom Transfer.

Frédéric AVENIER, Christian HERRERO, Winfried LEIBL, Alain DESBOIS, Régis GUILLOT, Jean-Pierre MAHY, Ally AUKAULOO
Angew. Chem. Int. Ed. 2013, 52, 3634–3637.

A synthon for the convenient and efficient introduction of tetrazolylmethyl groups into nucleophile-bearing compounds.
F. TOUTI, F. AVENIER, Q. LEFEBVRE, P. MAURIN, and J. HASSERODT
Eur. J. Org. Chem.
2010, 1928-1933.

Combining medium effects and cofactor catalysis: metallated synzymes accelerate phosphate transfer by 108.
F. AVENIER and F. HOLLFELDER
Chem. Eur. J. 2009, 15, 12371-12380.

Relating chemical and biological diversity space: a tunable system for efficient gene transfection.
L. D. VAN VLIET, M. R. CHAPMAN, F. AVENIER, C. Z. KITSON and F. HOLLFELDER
ChemBioChem. 2008, 9, 1960-1967.

Multiple aromatic amine insertion mediated by a diiron complex.
F. AVENIER, E. GOURE, P. DUBOURDEAUX, O. SENEQUE, J.L. ODDOU, J. PECAUT, S. CHARDON-NOBLAT, A. DERONZIER, J.M. LATOUR
Angew. Chem. Int. Ed. 2008, 47, 715-717.

Polyethylene Imine Derivatives (“Synzymes”) Accelerate Phosphate Transfer in the Absence of Metal.
F. AVENIER, J. B. DOMINGOS, L. D. VAN VLIET and F. HOLLFELDER
J. Am. Chem. Soc. 2007, 129, 7611-7619.

A diiron complex mediates an intramolecular aliphatic hydroxylation by various oxygen donors.
F. AVENIER, L. DUBOIS, P. DUBOURDEAUX, J. M. LATOUR
Chem. Commun. 2005, 480-482.

Catalytic aziridination of olefins and thioether amidation by a non-heme iron complex.
 F. AVENIER and J.-M. LATOUR,
Chem. Commun. 2004, 1544-1545.

Intramolecular aromatic hydroxylation mediated by a dinuclear iron complex: an oxo-FeIV FeIV active intermediate is suggested.
F. AVENIER, L. DUBOIS, J. M. LATOUR
New J. Chem. 2004, 28, 782-784.

Spectroscopic and electrochemical characterization of an aqua ligand exchange and oxidatively induced deprotonation in diiron complexes.
S. CHARDON-NOBLAT, O. HORNER, B. CHABUT, F. AVENIER, N. DEBEACKER, P. JONES, J. PECAUT, L. DUBOIS, C. JEANDEY, J.L. ODDOU, A. DERONZIER, J.M. LATOUR
Inorg. Chem. 2004, 43, 1638-1648.

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