Institut de Chimie Moléculaire et des Matériaux d'Orsay

Laboratoire de Chimie Bioorganique et Bioinorganique - LCBB

 

François Lambert

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Maître de Conférences (HDR)

UMR 8182, ICMMO
Institut de Chimie Moléculaire et des Matériaux d’Orsay
Université Paris-Sud, Bât 420
91405 Orsay Cedex

Tel: 33 (0) 1 69 15 47 25
Fax: 33 (0) 1 69 15 72 81

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Domaines de recherche / Research interests : Thème 2 / Subject 2

Mimes de site actifs d'enzymes non-hémiques : superoxydes dismutases (SOD) et oxygénases /Mimics of non-hemic enzyme active sites : superoxide dismutases (SOD) and oxygenases.

Enseignements / Teaching :

CAPES de Chimie-Physique

Agrégation de Sciences Physiques

Chimie générale et analytique / General and analytical chemistry

Publications / Publications (2001-2009) :

Synthesis and X-ray crystal structures of two transition metal complexes based on functionalized 1,5-anhydro-2-deoxy-D-galacticol and methyl 2-deoxy-a-D-galactopyranoside.
F. CISNETTI, R. GUILLOT, N. IBRAHIM, F. LAMBERT, M. THERISOD, and C. POLICAR
Carbohydr. Res. 2008, 343, 530-535.

A new pentadentate ligand forms both a di- and a mononuclear Mn(II) complex: electrochemical, spectroscopic and superoxide dismutase activity studies.
F. CISNETTI , A.-S. LEFEVRE, R. GUILLOT, F. LAMBERT, G. BLAIN, E. ANXOLABEHERE-MALLART, and C. POLICAR
Eur. J. Inorg. Chem. 2007, 4472-4480.


Series of Mn complexes based on N-centered ligands and superoxide – Reactivity in an anhydrous medium and SOD-like activity in an aqueous medium correlated to MnII/MnIII redox potentials.
S. DUROT, C. POLICAR, F. CISNETTI, F. LAMBERT, J.-P. RENAULT, G. PELOSI, G. BLAIN, H. KORRI-YOUSSOUFI, and J.-P. MAHY
Eur. J. Inorg. Chem.
2005, 3513-3523.

A pulse radiolysis study of catalytic superoxide radical dismutation by a manganese(II) complex with an N-tripodal ligand.
S. DUROT, F. LAMBERT, J.-P. RENAULT, and C. POLICAR
Eur. J. Inorg. Chem. 2005, 2789-2793.

Imidazole and imidazolate iron complexes: on the way for tuning 3D-structural characteristics and reactivity. Redox interconversions controled by protonation state.
F. LAMBERT, C. POLICAR, S. DUROT, M. CESARIO, L. YUWEI, H. KORRI-YOUSSOUFI, B. KEITA, and L. NADJO
Inorg. Chem. 2004, 43, 4178-4188.

Unusual efficiency of a non-heme iron complex as catalyst for the hydroxylation of aromatic compounds by hydrogen peroxide: comparison with irom porphyrins.          
J.-F. BARTOLI, F. LAMBERT, I. MORGENSTERN-BADARAU, P. BATTIONI, and D. MANSUY    
C. R. Chimie 2002, 5, 263-266.

New Mn(II) complexes with N/O coordination sphere from tripodal N-centered ligands. Characterization from solid state to solution and reaction with superoxide in non-aqueous media.      
C. POLICAR, S. DUROT, F. LAMBERT, M. CESARIO, F. RAMIANDRASOA, and I. MORGENSTERN-BADARAU
Eur. J. Inorg. Chem. 2001, 1807-1818.

 

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