Institut de Chimie Moléculaire et des Matériaux d'Orsay

Equipe de Recherche et d'Innovation en Electrochimie pour l'Energie (ERIEE)

Pierre Millet

Pierre Millet

 Professeur
 ERIEE - ICMMO - Bât 410
 Université Paris-Sud 11
 Rue du doyen Georges Poitou
 91405 Orsay Cedex
 FRANCE

 Tél : 01.69.15.48.12
  pierre.millet@u-psud.fr

 

Publications in peer-reviewed Journals

1- P. Millet, Synthesis and characterization of membrane-electrode assemblies. Application to water electrolysis, PhD thesis, Institut National Polytechnique de Grenoble (1989).
2- P. Millet, R. Durand, M. Pinéri, New Solid Polymer Electrolyte composites for water electrolysis, J. Appl. Electrochem., 19 (1989) 162-166.
3- P. Aldebert, F. Novel, M. Pinéri, P. Millet, C. Doumain, R. Durand, Preparation and characterization of SPE composites for electrolysers and fuel cells, Solid State Ionics, 35 (1989) 3-9.
4- R. Tétot, M. Benzakour, P. Millet, G. Boureau, Application of statistical thermodynamics to the study of non-stoechiometric compounds, Journal de Chimie Physique et de Physico-Chimie Biologique, 86-5 (1989) 1017-1021.
5- P. Millet, T. Alleau, P. Mathonnet, M. Pineri, R. Durand, Solid Polymer Electrolyte Water Electrolysis as a mean of Energy Storage for Space Applications, Air and Space Power J., ESA Ed., ESA SP-294 (1989) 245-249.
6- P. Millet, R. Durand, M. Pinéri, Preparation of new Solid Polymer Electrolyte composites for water electrolysis, Int. J. Hydrogen Energy, 15 (1990) 245-253.
7- P. Millet, Determination of self-diffusion coefficients from conductivity measurements in perfluorinated ionomer membranes, J. Membrane Sci., 50 (1990) 325-328.
8- P. Millet, Water electrolysis using EME technology : temperature profile inside a Nafion membrane during electrolysis, Electrochim. Acta, 36 (1990) 263-267.
9- A. Michas, P. Millet, Metal and metal oxides based membrane composites for Solid Polymer Electrolyte water electrolysis, J. Membrane Sci., 61 (1991) 157-165.
10- P. Millet, R. Durand, E. Dartyge, G. Tourillon, A. Fontaine, Study of the precipitation of metallic platinum into ionomers membranes by time-resolved dispersive X-ray spectroscopy, Synchrotron Radiation and Dynamic Phenomena, American Institute of Physics Ed., 258 (1991) 531-538.
11- P. Millet, T. Alleau, R. Durand, Characterization of membrane-electrodes assemblies for Solid Polymer Electrolyte water electrolysis, J. Appl. Electrochem., 23 (1993) 322.
12- P. Millet, R. Durand, E. Dartyge, G. Tourillon, A. Fontaine, Precipitation of metallic platinum into Nafion ionomer membranes- Experimental results, J. Electrochem. Soc., 140 (1993) 1373.
13- F. Andolfatto, R. Durand, A. Michas, P. Millet, P. Stevens, Solid Polymer Electrolyte water electrolysis : electrocatalysis and long term stability, Int. J. Hydrogen Energy, 19 (1994) 421-427.
14- P. Millet, Water electrolysis using EME technology : electric potential distribution inside a Nafion membrane during electrolysis, Electrochim. Acta, 39 (1994) 2501-2506.
15- P. Millet, F. Andolfatto, R. Durand, Preparation of Solid Polymer Electrolyte Composites. Investigation of the ion-exchange process, J. Appl. Electrochem., 25 (1995) 227-232.
16- P. Millet, F. Andolfatto, R. Durand, Preparation of Solid Polymer Electrolyte Composites. Investigation of the precipitation process, J. Appl. Electrochem. 25 (1995) 233-239.
17- H. Y. Caï, P. Millet, P. Dantzer, Intermetallic hydrides. (I) Investigation of the rate of phase transformation, J. Alloys Comp., 231 (1995) 427-433.
18- P. Millet, F. Andolfatto, R. Durand, Design and performances of a Solid Polymer Electrolyte water electrolyser, Int. J. Hydrogen Energy, 21 (1996) 87-96.
19- P. Millet, Electric potential distribution in an electro-chemical cell, J. Chem. Educ., 73 (1996) 956-961.
20- P. Millet, A. Michas, R. Durand, A Solid Polymer Electrolyte – based ethanol gas sensor, J. Appl. Electrochem., 26 (1996) 933-937.
21- P. Millet, P. Dantzer, A new approach to the kinetics of LaNi5 - H2(g) systems based on impedance spectroscopy analysis, J. Alloys Comp., 253 (1997) pp. 542-546.
22- P. Millet, Noble metal - membrane composites for electrochemical applications, J. Chem. Edu., 76 (1999) 47-49.
23- P. Millet, P. Dantzer, Impedance of metal hydride electrodes. Rate of phase transformation limited by nucleation and growth mechanisms, Electrochem. Com., 1 (1999) 163.
24- P. Dantzer, P. Millet, Advances in hydride phase growth : automatic high precision calorimeter – volumetric devices, for thermodynamic and kinetics analyses, Rev. Sci. Instrum., 71 (2000) 142-153.
25- P. Dantzer, P. Millet, T. Flanagan, Thermodynamic characterization of hydride phase growth in ZrNi-H2, Metallurgical and Materials Transactions A, 32 (2001) 29-38.
26- P. Dantzer, P. Millet, Heat flux calorimetry in intermetallic compound - H2(g) systems : heat measurements and modeling in the low pressures range, Thermochimica Acta, 370 (2001) 1-14.
27- P. Millet, M. Srour, R. Faure and R. Durand, A study of the hydrogen absorption and desorption reactions in palladium electrodes using the potential step method, Electrochem. Com., 3 (2001) 478-482.
28- P. Dantzer, P. Millet, On the accuracy of heat flux calorimetry in stable intermetallic-H2(g) systems, J. Alloys Comp., 330-332 (2002) 34-40.
29- N. Michel, S. Poulat, P. Millet, P. Dantzer, L. Priester, M. Gupta, ZrNi-H2 : microstructural analysis of the thermodynamically controlled hydride phase growth, and electronic properties, J. Alloys Comp., 330-332 (2002) 280-286.
30- P. Millet, P. Dantzer, Hydriding kinetics analysis by the frequency response method. Application to the ZrNi-H2(g) system, J. Alloys Comp., 330-332 (2002) 476-482.
31- P. Millet, Thermodynamic paths in the two-phase domain of the PdH system and a method for kinetic analysis, Electrochem. Com., 7 (2005) 40-44.
32- P. Millet, Pneumato-chemical impedance spectroscopy : (I) principles, J. Phys. Chem., 109 (2005) 24016 – 24024.
33- P. Millet, Pneumato-chemical impedance spectroscopy : (II) dynamics of hydrogen sorption by metals, J. Phys. Chem., 109 (2005) 24025-24030.
34- P. Millet, L’électrolyse de l’eau à membrane acide, Techniques de l’ingénieur, J4810 (2006) ; French Publication.
35- P. Millet, Le réacteur électrochimique, Techniques de l’ingénieur, J4802 (2006) ; French Publication.
36- O. Pantani, E. Anxolabéhère - Mallart, A. Aukauloo, P. Millet, Electroactivity of cobalt and nickel glyoximes with regard to the electro-reduction of protons into molecular hydrogen in acidic media, Electrochem. Commun., 9 (2007) 54-58.
37- P. Millet, S.A. Grigoriev, Pneumato-chemical impedance spectroscopy for analyzing hydrogen sorption and desorption reactions in metal hydride systems, Int. Sci. J. Altern. En. and Eco., 47-3 (2007) 25-31.
38- P. Millet, C. Decaux, R. Ngameni, M. Guymont, Fourier domain analysis of hydriding kinetics using pneumato-chemical impedance spectroscopy, Research Letters in Physical-Chemistry, 96251 (2007) 1-5; doi:10.1155/2007/96251.
39- P. Millet, C. Decaux, R. Ngameni, M. Guymont, Experimental requirements for measuring pneumato-chemical impedances, Rev. Sci. Instrum. 78 (2007) 123902-1 to 123902-11.
40- S. Grigoriev, P. Millet, V. N. Fateev, Evaluation of carbon-supported Pt and Pd nanoparticles for the hydrogen evolution reaction in PEM water electrolysers, J. Power Sources, 177 (2008) 281-285.
41- P. Millet, C. Lebouin, R. Ngameni, A. Ranjbari, M. Guymont, Hydriding reaction of LaNi5. Correlations between thermodynamic states and sorption kinetics during activation, Research Letters in Physical-Chemistry, 346545 (2008) 1-4; doi:10.1155/2008/346545.
42- O. Pantani, S. Kaskar, R. Guillot, P. Millet, E. Anxolabéhère, A. Aukauloo, Cobalt Clathrochelate Complexes as Hydrogen-Producing Catalysts, Angewandte Chemie Int. Ed. 120 (2008) 10096-10098.
43- S. Grigoriev, L.I. Ilyukhina, P.H. Middleton, P. Millet, T.O. Saetre, V. N. Fateev, A comparative evaluation of palladium and platinum nanoparticles as catalysts in PEM electrochemical cells, Int. J. Nuc. Hydrogen Prod. and Appl., 1-4 (2008) 343-354
44- S.A. Grigoriev, P. Millet, S.A. Volobuev, V.N. Fateev, Optimization of porous current collectors for PEM water electrolysers, Int. J. Hydrogen Energy, 34 (2009) 4968-4973.
45- C. Lebouin, Y. soldo, E. Siebert, P. Millet, M. Maret, R. Faure, Electrochemically elaborated palladium nanofilms on Pt(111): characterization and hydrogen insertion study, J. Electroanal. Chem, 626 (2009) 59-65.
46- P. Millet, D. Dragoe, S. Grigoriev, V. Fateev, C. Etievant, GenHyPEM : a research program on PEM water electrolysis supported by the European Commission, Int. J. Hydrogen Energy, 34 (2009) 4974-4982.
47- P. Millet, C. Lebouin, A. Ranjbari, R. Ngameni, M. Guymont, Characterization of Metal hydrides using pneumato-chemical impedance spectroscopy, Int. J. Hydrogen Energy, 34 (2009) 4990-4996.
48- G. Doucet, C. Etiévant, C. Puyenchet, S. Grigoriev, P. Millet, Hydrogen-based PEM auxiliary power unit, Int. J. Hydrogen Energy, 34 (2009) 4983-4989.
49- C. Decaux, T. Mehdoui, R. Ngameni, A. Ranjbari, P. Millet, Frequency-domain analysis of hydrogen permeation across Pd77Ag23 metallic membranes, Int. J. Hydrogen Energy, 34 (2009) 5003-5009.
50- S.A. Grigoriev, V.N. Fateev, P. Millet, S.V. Korobtsev, V.I. Porembskiy, M. Pepic, C. Etievant, C. Puyenchet, Hydrogen safety aspects related to high-pressure PEM water electrolysis, Int. J. Hydrogen Energy, 34 (2009) 5986-5991.
51- S.A. Grigoriev, A.A. Kalinnikov, P. Millet, V.I. Porembsky, V.N. Fateev, Mathematical modeling of high pressure PEM water electrolysis, J. Applied Electrochem., 40, 5 (2010) 921-932.
52- P. Millet, R. Ngameni, S.A. Grigoriev, N. Mbemba, F. Brisset, A. Ranjbari, C. Etiévant, PEM water electrolyzers : from electrocatalysis to stack development, Int. J. Hydrogen Energy, 35 (2010) 5043-5052.
53- C. Decaux, R. Ngameni, D. Solas, S. Grigoriev, P. Millet, Time and frequency domains analysis of hydrogen permeation across PdCu metallic membranes for hydrogen purification, Int. J. Hydrogen Energy, 35 (2010) 4883-4892.
54- S.A. Grigoriev, P. Millet, P.H. Middleton, T.O. Saetre, V.N. Fateev, Design and characterization of bi-functional electrocatalytic layers for application in PEM unitized regenerative fuel cells, Int. J. Hydrogen Energy, 35 (2010) 5070-5076.
55- S.A. Grigoriev, V.I. Porembskiy, S.V. Korobtsev, V.N. Fateev, F. Auprêtre, P. Millet, High pressure PEM water electrolysis and corresponding safety issues, Int. J. Hydrogen Energy, 36 (2011) 2721-2728.
56- P. Millet, N. Mbemba, S.A. Grigoriev, V.N. Fateev, A. Aukauloo, C. Etievant, Electrochemical performances of PEM water electrolysis cells and perspectives, Int. J. Hydrogen Energy, 36 (2011) 4134-4142.
57- R. NgameNi, P. Millet, S.A. Grigoriev, V.N. Fateev, C. Etievant, Scientific and engineering issues related to PEM technology: Water electrolysers, fuel cells and unitized regenerative systems, Int. J. Hydrogen Energy, 36 (2011) 4156-4163.
58- R. NgameNi, N. Mbemba, S.A. Grigoriev, P. Millet, Comparative analysis of the hydriding kinetics of LaNi5, La0.8Nd0.2Ni5 and La0.7Ce0.3Ni5 compounds, Int. J. Hydrogen Energy, 36 (2011) 4178-4184.
59- P. Millet, R. Ngameni, C. Decaux, S. Grigoriev, Hydrogen sorption by Pd77Ag23 metallic membranes. Role of hydrogen content, temperature and sample microstructure, Int. J. Hydrogen Energy, 36 (2011) 4262-4269.
60- S.A. Grigoriev, P. Millet, V.I. Porembsky, V.N. Fateev, Development and preliminary testing of a unitized regenerative fuel cell based on PEM technology, Int. J. Hydrogen Energy, 36 (2011) 4164-4168.
61- S.A. Grigoriev, I.G. Shtatniy, P. Millet, V.I. Porembsky, V.N. Fateev, Description and characterization of an electrochemical hydrogen compressor/concentrator based on solid polymer electrolyte technology, Int. J. Hydrogen Energy, 36 (2011) 4148-4155.
62- S.A. Grigoriev, M.S. Mamat, K.A. Dzhus, G.S. Walker, P. Millet, Platinum and palladium nanoparticles supported by Graphitic nanofibres as catalysts for PEM water electrolysis, Int. J. Hydrogen Energy, 36 (2011) 4143-4147.
63- P. Millet, R. Ngameni, Non-harmonic electro-chemical and pneumato-chemical impedance spectroscopies for analyzing the hydriding kinetics of palladium, Electrochimica Acta, 56 (23) (2011) 7907-7915.
64- S.A. Grigoriev, A.A. Kalinnikov, A.A. Filippov, M.–T. Nguyen, P. Millet, V.N. Fateev, Characterisation of a hydrogen concentration/compression PEM cell using electrochemical impedance spectroscopy, J. Applied Electrochem., 41 (2011) 1033-1042.
65- M-T. Dinh Nguyen, A. Ranjbari, L. Catala, F. Brisset, P. Millet, A. Aukauloo, Implementing Molecular Catalysts for Hydrogen Production in Proton Exchange Membrane Water Electrolysers, Coord. Chem. Review, 256 (2012) 2435 – 2444.
66- P. Millet, F. de Guglielmo, S.A. Grigoriev, V.I. Porembskiy, Cell failure mechanisms in PEM water electrolyzers, Int. J. Hydrogen Energy, 37 (2012) 17478-17487.
67- P. Millet (invited paper), Electrochemical impedance spectroscopy using exponentially-rising voltage steps. (I) Analysis of a model electrical circuit, Bulg. Chem. Com. 44 (4) (2012) 1-8.
68- P. Millet (invited paper), Electrochemical impedance spectroscopy using exponentially-rising voltage steps. (II) Analysis of the hydrogen electro-insertion into palladium foils, Bulg. Chem. Com. 44 (4) (2012) 9-18.
69- P. Millet, S.A. Grigoriev, V.I. Porembskiy, Development and characterisation of a pressurized PEM Bi-stack electrolyzer, Int. J. Energy Research, 37 (2013) 449-456.
70- C. Lebouin, Y. Soldo, P. Millet, Kinetics of hydrogen sorption by palladium nanoparticles, Int. J. Hydrogen Energy, 38 (2013) 966-972.
71- A.A. Fedotov, S.A. Grigoriev, E.K. Lyutikova, P. Millet, V.N. Fateev, Characterization of carbon-supported platinum nano-particles synthesized using magnetron sputtering for application in PEM electrochemical systems, Int. J. Hydrogen Energy, 38 (2013) 426-430.
72- C. Decaux, R. Ngameni, A. Ranjbari, S. Grigoriev, P. Millet, Dynamics of hydrogen permeation across metallic membranes, Int. J. Hydrogen Energy, 38 (2013) 8584–8589.
73- N. Mbemba, C. Herrero, A. Ranjbari, A. Aukauloo, S.A. Grigoriev, P. Millet, Ruthenium-based molecular compounds for oxygen evolution in acidic media, Int. J. Hydrogen Energy, 38-20 (2013) 8590-8596.
74- S.A. Grigoriev, A.A. Kalinnikov, N.V. Kuleshov, P. Millet, Numerical optimization of bipolar plates and gas diffusion electrodes for PBI-based PEM fuel cells, Int. J. Hydrogen Energy,38-20 (2013) 8557-8567.
75- A.A. Fedotov, S.A. Grigoriev, P. Millet, V.N. Fateev, Plasma-assisted Pt and Pt-Pd nano-particles deposition on carbon carriers for application in PEM electrochemical cells, Int. J. Hydrogen Energy, 38-20 (2013) 8568-8574.
76- R. Ngameni, P. Millet, EIS analysis of hydrogen incorporation into Pd-based planar, spherical and cylindrical bi-layers, Electrochimica Acta, 131 (2014) 52-59.
77- C. Rozain, P. Millet, Electrochemical characterization of Polymer Electrolyte Membrane Water Electrolysis Cells, Electrochimica Acta, 131 (2014) 160-167.
78- K.A. Dzhus, S.A. Grigoriev, D.G. Bessarabov, P. Millet, Failure of PEM water electrolysis cells: Case study involving anode dissolution and membrane thinning, Int. J. Hydrogen Energy 39(15) (2014) 20440-20446.
79- P. Millet and S.A. Grigoriev, Electrochemical characterization and optimization of a PEM water electrolysis stack for hydrogen generation, Chem. Engineering. Trans, Vol. 41 (2014) doi:10.3303/CET1441002.
80- P. Millet, C. Rozain, A. Villagra, A. Ragupathy, A. Ranjbari and M. Guymont, Implementation of cobalt clathrochelates in polymer electrolyte water electrolysers for hydrogen evolution, Chem. Engineering. Trans, Vol. 41 (2014) doi:10.3303/CET1441055.
81- S.A. Grigoriev, N. V. Kuleshov, P. Millet, Electrochemical Characterization of a High-Temperature Proton-Exchange Membrane Fuel Cell Using Doped-Poly Benzimidazole as Solid Polymer Electrolyte, Journal of Fuel Cell Science and Technology, 12(3) (2015) 1045-1049, doi: 10.1115/1.4029873
82- S.?. Grigoriev, A.A. Fedotov, V.Yu. Murzin, E.V. Khramov, Ya.V. Zubavichus, P. Millet, V.N. Fateev, Synthesis by magnetron-ion sputtering and characterization of nanostructured electrocatalysts made of nanocarbon carriersmetallized with platinum,Russian Journal of Electrochemistry, in press.
83- C. Rozain, N. Guillet, E. Mayousse, P. Millet, Influence of iridium oxide loadings on the performance of PEM water electrolysis cells, Electrochimica Acta, accepted for publication.
84- C. Rozain, N. Guillet, E. Mayousse, P. Millet, PEM water electrolysis performances obtained with reduced iridium contents at the anode, Int. J. Hydrogen Energy, accepted for publication.